Citation: Xiaotong Wang, Yanmin Li, Xin Liu, Shanmin Gao, Baibiao Huang, Ying Dai. Preparation of Ti³⁺ self-doped TiO₂ nanoparticles and their visible light photocatalytic activity[J]. Chinese Journal of Catalysis, ;2015, 36(3): 389-399. doi: 10.1016/S1872-2067(14)60234-5 shu

Preparation of Ti³⁺ self-doped TiO₂ nanoparticles and their visible light photocatalytic activity

Xiaotong Wang ^a ,
Yanmin Li ^b,, ,
Xin Liu ^a ,
Shanmin Gao ^a,c,, ,
Baibiao Huang ^c ,
Ying Dai ^c

1.
a College of Chemistry and Materials Science, Ludong University, Yantai 264025, Shandong, China;

Corresponding author: Yanmin Li, Shanmin Gao,
Received Date: 1 September 2014
Available Online: 29 September 2014
Fund Project: 国家重点基础研究发展计划(973计划, 2013CB632401) (973计划, 2013CB632401) 山东省自然科学基金重点项目(ZR2013EMZ001) (ZR2013EMZ001) 山东省高等学校科技计划(J12LA01). (J12LA01)

Ti³⁺ self-doped TiO₂nanoparticles were synthesized by hydrothermal treatment of a gel precursor obtained using TiH₂ as the Ti source and H₂O₂ as oxidant. The effects of different states of gel and hydrothermal treatment time on the properties of the samples were studied. The structure, crystallinity, morphology, and optical properties of the nanoparticles were characterized by X-ray diffraction, transmission electron microscopy, high-resolution transmission electron microcopy, and UV-visible diffuse reflectance spectroscopy. The chemical states of Ti and O were confirmed by X-ray photoelectron spectroscopy and electron spin resonance spectroscopy. Methylene blue (MB) solutions were used as simulated wastewater to evaluate the visible-light photocatalytic activity of the samples. The samples exhibited strong absorption in the visible light region compared with pure TiO₂and an excellent performance in the photocatalytic degradation of MB. When yellow gel was used as the precursor, the sample obtained after hydrothermal treatment at 160 ℃ for 24 h exhibited the best visible light photocatalytic activity with a reaction rate constant of 0.0439 min^-1, 18.3 times that of pure TiO₂. The samples also showed excellent cyclic stability of the photocatalytic activity.
- Ti³⁺self-doped,
- Titanium oxide,
- Gel,
- Hydrothermal method,
- Visible light photocatalysis
1. [1]
  [1] Thompson T L, Yates J T Jr. Chem Rev, 2006, 106: 4428
2. [2]
  [2] Xu P, Xu T, Lu J, Gao S M, Hosmane N S, Huang B B, Dai Y, Wang Y B. Energ Environ Sci, 2010, 3: 1128
3. [3]
  [3] Li H Y, Liu J F, Qian J J, Li Q Y, Yang J J. Chin J Catal(李海燕, 刘金凤, 钱俊杰, 李秋叶, 杨建军. 催化学报), 2014, 35: 1578
4. [4]
  [4] Chen Y C, Pu Y C, Hsu Y J. J Phys Chem C, 2012, 116: 2967
5. [5]
  [5] Huang Y, Li K X, Yan L S, Dai Y H, Huang Z M, Xue K P, Guo H Q, Xiong J J. Chin J Catal (黄燕, 李可心, 颜流水, 戴玉华, 黄智敏, 薛昆鹏, 郭会琴, 熊晶晶. 催化学报), 2012, 33: 308
6. [6]
  [6] Kochuveedu S T, Kim D P, Kim D H. J Phys Chem C, 2012, 116: 2500
7. [7]
  [7] Singh S K, Chauhan R, Singh B, Diwan K, Kociok-Köhn G, Bahadur L, Singh N. Dalton Trans, 2012, 41: 1373
8. [8]
  [8] Hoffman M R, Martin S T, Choi W, Bahnemann D W. Chem Rev, 1995, 95: 69
9. [9]
  [9] Tachikawa T, Fujitsuka M, Majima T. J Phys Chem C, 2007, 111: 5259
10. [10]
  [10] Valentin C D, Pacchioni G, Selloni A. J Phys Chem C, 2009, 113: 20543
11. [11]
  [11] Kuznetsov A I, Kameneva O, Alexandrov A, Bityurin N, Chhor K, Kanaev A. J Phys Chem B, 2006, 110: 435
12. [12]
  [12] Lira E, Wendt S, Huo P P, Hansen J, Streber R, Porsgaard S, Wei Y Y, Bechstein R, Lægsgaard E, Besenbacher F. J Am Chem Soc, 2011, 133: 6529
13. [13]
  [13] Teleki A, Pratsinis S E. Phys Chem Chem Phys, 2009, 11: 3742
14. [14]
  [14] Komaguchi K, Maruoka T, Nakano H, Imae I, Ooyama Y, Harima Y. J Phys Chem C, 2010, 114: 1240
15. [15]
  [15] Zuo F, Wang L, Wu T, Zhang Z Y, Borchardt D, Feng P Y. J Am Chem Soc, 2010, 132: 11856
16. [16]
  [16] Wang W, Lu C H, Ni Y R, Su M X, Xu Z Z. Appl Catal B, 2012, 127: 28
17. [17]
  [17] Liu Y C, Xing M Y, Zhang J L. Chin J Catal(刘允昌, 邢明阳, 张金龙. 催化学报), 2014, 35: 1511
18. [18]
  [18] Xing M Y, Fang W Z, Nasir M, Ma Y F, Zhang J L, Anpo M. J Catal, 2013, 297: 236
19. [19]
  [19] Fang W Z, Xing M Y, Zhang J L. Appl Catal B, 2014, 160: 240
20. [20]
  [20] Liu X, Xu H, Grabstanowicz L R, Gao S M, Lou Z Z, Wang W J, Huang B B, Dai Y, Xu T. Catal Today, 2014, 225: 80
21. [21]
  [21] Grabstanowicz L G, Gao S M, Li T, Rickard R M, Rajh T, Liu D J, Xu T. Inorg Chem, 2013, 52: 3884
22. [22]
  [22] Liu X, Gao S M, Xu H, Lou Z Z, Wang W J, Huang B B, Dai Y. Nanoscale, 2013, 5: 1870
23. [23]
  [23] Sandim H R Z, Morante B V, Suzuki P A. Mater Res, 2005, 8: 293
24. [24]
  [24] Natoli A, Cabeza A, De La Torre A G, Aranda M A G, Santacruz I. J Am Ceram Soc, 2012, 95: 502
25. [25]
  [25] Yu F H, Wang J H, Zhao K F, Yin J, Jin C Z, Liu X. Chin J Catal(于福海, 王军虎, 赵昆峰, 尹杰, 金长子, 刘忻. 催化学报), 2013, 34: 1216
26. [26]
  [26] Etacheri V, Seery M K, Hinder S J, Pillai S C. Chem Mater, 2010, 22: 3843
27. [27]
  [27] Asiltürk M, Sayílkan F, Arpaç E. J Photochem Photobiol A, 2009, 203: 64
28. [28]
  [28] Xing M Y, Zhang J L, Chen F, Tian B Z. Chem Commun, 2011, 47: 4947
29. [29]
  [29] Vijay M, Ananthapadmanabhan P V, Sreekumar K P. Appl Surf Sci, 2009, 255: 9316
30. [30]
  [30] Zou J, Gao J C, Wang Y. J Photochem Photobiol A, 2009, 202: 128
31. [31]
  [31] Joung S K, Amemiya T, Murabayashi M, Itoh K. Appl Catal A, 2006, 312: 20
32. [32]
  [32] Uno M, Kosuga A, Okui M, Horisaka K, Yamanaka S. J Alloys Compd, 2005, 400: 270
33. [33]
  [33] Szczepankiewicz S H, Moss J A, Hoffmann M R. J Phys Chem B, 2002, 106: 2922
34. [34]
  [34] Liu G, Yan X X, Chen Z G, Wang X W, Wang L Z, Lu G Q, Cheng H H. J Mater Chem, 2009, 19: 6590
35. [35]
  [35] Suriye K, Jongsomjit B, Satayaprasert C, Praserthdam P. Appl Surf Sci, 2008, 255: 2759
36. [36]
  [36] Suriye K, Praserthdam P, Jongsomjit B. Appl Surf Sci, 2007, 253: 3849
37. [37]
  [37] Kong M, Li Y Z, Chen X, Tian T T, Fang P F, Zhang F, Zhao X J. J Am Chem Soc, 2011, 133: 16414
38. [38]
  [38] Su J, Zou X X, Zou Y C, Li G D, Wang P P, Chen J S. Inorg Chem, 2013, 52: 5924
39. [39]
  [39] Cronemeyer D C. Phys Rev, 1959, 113: 1222
40. [40]
  [40] Heller A, Degani Y, Johnson D W, Gallagher P K. J Phys Chem, 1987, 91: 5987
1. [1]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
2. [2]
  Tongyan Yu , Pan Xu . Visible-Light Photocatalyzed Radical Rearrangement Reaction. University Chemistry, 2025, 40(7): 169-176. doi: 10.12461/PKU.DXHX202409070
3. [3]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
4. [4]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
5. [5]
  Dan Liu . 可见光-有机小分子协同催化的不对称自由基反应研究进展. University Chemistry, 2025, 40(6): 118-128. doi: 10.12461/PKU.DXHX202408101
6. [6]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
7. [7]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
8. [8]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
9. [9]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 2402016-0. doi: 10.3866/PKU.WHXB202402016
10. [10]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
11. [11]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
12. [12]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
13. [13]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
14. [14]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
15. [15]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
16. [16]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
17. [17]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
18. [18]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
19. [19]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
20. [20]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201

Get Citation

PDF

XML

Metrics

PDF Downloads(230)
Abstract views(786)
HTML views(58)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Ti3+ self-doped TiO2 nanoparticles and their visible light photocatalytic activity

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Ti³⁺ self-doped TiO₂ nanoparticles and their visible light photocatalytic activity