Citation: Furong Wang, Sisi Tang, Yinghao Yu, Lefu Wang, Biaolin Yin, Xuehui Li. Preparation of palladium nanoparticle catalyst in ionic liquid and its catalytic properties for Heck-Mizoroki reaction[J]. Chinese Journal of Catalysis, ;2014, 35(12): 1921-1926. doi: 10.1016/S1872-2067(14)60224-2 shu

Preparation of palladium nanoparticle catalyst in ionic liquid and its catalytic properties for Heck-Mizoroki reaction

1.
School of Chemistry and Chemical Engineering, State Key Laboratory of Pulp and Paper Engineering of China, South China University of Technology, Guangzhou 510640, Guangdong, China

Corresponding author: Xuehui Li,
Received Date: 4 July 2014
Available Online: 3 September 2014
Fund Project: 国家自然科学基金(21336002和21276094) (21336002和21276094)高等学校博士学科点专项科研基金(20130172110043). (20130172110043)

A palladium nanoparticle (PdNPs) catalyst was synthesized in halogen-free anion ionic liquid (1-buthyl-3-methylimidazolium lactate, [Bmim]Lac) by a simple chemical approach. The transmission electron microscopy analysis confirmed the presence of highly dispersed PdNPs in [Bmim]Lac with small average particle size distribution from 2.2 to 3.1 nm. The size of the PdNPs increases with decreasing molar ratio of [Bmim]Lac to Pd(OAc)₂ and increasing temperature. The activity of PdNPs@[Bmim]Lac catalyst was tested by the Heck-Mizoroki reaction, and the conditions were optimized. The catalyst can efficiently catalyze couplings of various aryl bromides and iodides with different olefins, giving good yields of products under the optimal conditions and be recycled up to six consecutive times.
- Palladium nanoparticles,
- Heck-Mizoroki reaction,
- 1-Buthyl-3-methylimidazolium lactate,
- Green ionic liquid
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