Citation: Zhijuan Zou, Hao Cheng, Jingyu Wang, Xijiang Han. Pyrolyzed titanium dioxide/polyaniline as an efficient non-noble metal electrocatalyst for oxygen reduction reaction[J]. Chinese Journal of Catalysis, ;2015, 36(3): 414-424. doi: 10.1016/S1872-2067(14)60223-0 shu

Pyrolyzed titanium dioxide/polyaniline as an efficient non-noble metal electrocatalyst for oxygen reduction reaction

Zhijuan Zou ^a ,
Hao Cheng ^a ,
Jingyu Wang ^a,b,, ,
Xijiang Han ^a,,

1.
a Department of Chemistry, Harbin Institute of Technology, Harbin 150001, Heilongjiang, China;

Corresponding author: Jingyu Wang, Xijiang Han,
Received Date: 13 July 2014
Available Online: 4 September 2014
Fund Project: 国家自然科学基金(21001037, 21071037, 91122002) (21001037, 21071037, 91122002) 哈尔滨技术创新人才专项基金(2013RFLXJ011) (2013RFLXJ011) 华中科技大学引进人才科研基金(2014036). (2014036)

To overcome the prohibitive cost and poor durability of conventional Pt-based catalysts, TiO₂/C was prepared by pyrolyzing a novel titanium dioxide/polyaniline (TiO₂/PANI) composite. The prepared catalysts were characterized by scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, cyclic voltammetry (CV), and linear sweep voltammetry. Interaction between PANI and TiO₂ was found to inhibit the aggregation of TiO₂ and its transformation from anatase to rutile. The catalytic activity of the TiO₂/C first increased with increasing PANI content and then decreased; the optimum was achieved when the PANI/TiO₂ mass ratio was 35/100. CV and i-t curves showed that the prepared composite has a good catalytic stability.
- Polyaniline,
- Titania,
- Pyrolyzation,
- Cathode catalyst,
- Oxygen reduction reaction
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