Citation: Yahui Sun, Zhenping Qu, Dan Chen, Hui Wang, Fan Zhang, Qiang Fu. Formaldehyde catalytic oxidation over hydroxyapatite modified with various organic molecules[J]. Chinese Journal of Catalysis, ;2014, 35(12): 1927-1936. doi: 10.1016/S1872-2067(14)60129-7 shu

Formaldehyde catalytic oxidation over hydroxyapatite modified with various organic molecules

Yahui Sun ^a ,
Zhenping Qu ^a,, ,
Dan Chen ^a ,
Hui Wang ^a ,
Fan Zhang ^b ,
Qiang Fu ^b

1.
a. Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian116024, Liaoning, China;

Corresponding author: Zhenping Qu,
Received Date: 13 April 2014
Available Online: 28 April 2014
Fund Project: 国家自然科学基金(21377016) (21377016) 中央高校基本科研业务费专项资金(DUT13LK27) (DUT13LK27) 长江学者和创新团队发展计划 (IRT_13R05). (IRT_13R05)

Hydroxyapatite (HAP) was modified by adding various organic molecules, such as cetyltrimethylammonium bromide, sodium dodecyl sulfate, and sodium citrate, during the precipitation of HAP. Sodium citrate-modified HAP displayed the best activity for formaldehyde oxidation, achieving complete conversion at 240 ℃. The influence of the organic modifiers on the structure of HAP was assessed by X-ray diffraction, Fourier transform infrared spectroscopy, N₂ adsorption- desorption, scanning electron microscopy, and thermogravimetry/derivative thermogravimetry. The higher specific surface area and pore volume, and smaller pores, owing to modification with sodium citrate, favored adsorption, mass transfer, and interaction process during formaldehyde oxidation. Furthermore, the higher hydroxyl group content observed in sodium citrate- modified HAP enhanced interactions between formaldehyde and HAP, thus resulting in higher catalytic activity.
- Modified hydroxyapatite,
- Sodium citrate,
- Specific surface area,
- Hydroxyl group,
- Formaldehyde catalytic oxidation
1. [1]
  [1] Pei J J, Zhang J S. HVAC&R Res, 2011, 17: 476
2. [2]
  [2] Yu C, Crump D. Build Environ, 1998, 33: 357
3. [3]
  [3] Jia M L, Shen Y N, Li C Y, Bao Z, Sheng S S. Catal Lett, 2005, 99: 235
4. [4]
  [4] Zhang C B, He H, Tanaka K. Catal Commun, 2005, 6: 211
5. [5]
  [5] Peng J X, Wang S D. Appl Catal B, 2007, 73: 282
6. [6]
  [6] Qu Z P, Shen S J, Chen D, Wang Y. J Mol Catal A, 2012, 356: 171
7. [7]
  [7] Tang X F, Li Y G, Huang X M, Xu Y D, Zhu H Q, Wang J G, Shen W J. Appl Catal B, 2006, 62: 265
8. [8]
  [8] Liu X S, Lu J Q, Qian K, Huang W X, Luo M F. J Rare Earths, 2009, 27: 418
9. [9]
  [9] Wang R H, Li J H. Catal Lett, 2009, 131: 500
10. [10]
  [10] Tang X F, Chen J L, Huang X M, Xu Y D, Shen W J. Appl Catal B, 2008, 81: 115
11. [11]
  [11] Li C Y, Shen Y N, Jia M L, Sheng S S, Adebajo M O, Zhu H Y. Catal Commun, 2008, 9: 355
12. [12]
  [12] Ma C Y, Wang D H, Xue W J, Dou B J, Wang H L, Hao Z P. Environ Sci Technol, 2011, 45: 3628
13. [13]
  [13] Tang X F, Chen J L, Li Y G, Li Y, Xu Y D, Shen W J. Chem Eng J, 2006, 118: 119
14. [14]
  [14] Zhang C B, He H, Tanaka K. Appl Catal B, 2006, 65: 37
15. [15]
  [15] Sierra P, Chakrabarti S, Tounkara R, Loranger S, Kennedy G, Zayed J. Environ Res, 1998, 79: 94
16. [16]
  [16] Reaney S H, Kwik-Uribe C L, Smith D R. Chem Res Toxicol, 2002, 15: 1119
17. [17]
  [17] Zhao D Z, Ding T Y, Li X S, Liu J L, Shi C, Zhu A M. Chin J Catal (赵德志, 丁大英, 李小松, 刘景林, 石川, 朱爱民. 催化学报), 2012, 33: 396
18. [18]
  [18] Ma L, Wang D S, Li J H, Bai B Y, Fu L X, Li Y D. Appl Catal B, 2014, 148-149: 36
19. [19]
  [19] Bai B Y, Arandiyan H, Li J H. Appl Catal B, 2013, 142-143: 677
20. [20]
  [20] Wei R C, Chen H L, Zhang X M, Suo J S. Chin J Catal (魏日出, 陈洪林, 张小明, 索继栓. 催化学报), 2013, 34: 1945
21. [21]
  [21] Park S M, Jeon S W, Kim S H. Catal Lett, 2014, 144: 756
22. [22]
  [22] An N H, Wu P, Li S Y, Jia M J, Zhang W X. Appl Surf Sci, 2013, 285: 805
23. [23]
  [23] Low H R, Avdeev M, Ramesh K, White T J. Adv Mater, 2012, 24: 4175
24. [24]
  [24] Xu J, White T, Li P, He C H, Han Y F. J Am Chem Soc, 2010, 132: 13172
25. [25]
  [25] Gopi D, Indira J, Nithiya S, Kavitha L, Kamachi Mudali U, Kanimozhi K. Bull Mater Sci, 2013, 36: 799
26. [26]
  [26] Yan H, Hao L J, Zhao N R, Huang M J, Du C, Wang Y J. Mater Chem Phys, 2013, 141: 488
27. [27]
  [27] Yan L, Li Y D, Deng Z X, Zhuang J, Sun X M. Int J Inorg Mater, 2001, 3: 633
28. [28]
  [28] Wang H L, Zhai L F, Li Y H, Shi T J. Mater Res Bull, 2008, 43: 1607
29. [29]
  [29] Dominguez M I, Romero-Sarria F, Centeno M A, Odriozola J A. Appl Catal B, 2009, 87: 245
30. [30]
  [30] Wang A L, Liu D, Yin H B, Wu H X, Wada Y, Ren M, Jiang T S, Cheng X N, Xu Y Q. Mater Sci Eng C, 2007, 27: 865
31. [31]
  [31] Diaz A, Lopez T, Manjarrez J, Basaldella E, Martinez-Blanes J M, Odriozola J A. Acta Biomater, 2006, 2: 173
32. [32]
  [32] Tounsi H, Djemal S, Petitto C, Delahay G. Appl Catal B, 2011, 107: 158
33. [33]
  [33] Boukha Z, Kacimi M, Ziyad M, Ensuque A, Bozon-Verduraz F. J Mol Catal A, 2007, 270: 205
34. [34]
  [34] Shum H C, Bandyopadhyay A, Bose S, Weitz D A. Chem Mater, 2009, 21: 5548
35. [35]
  [35] Gajbhiye N S, Balaji G. Thermochim Acta, 2002, 385: 143
36. [36]
  [36] Wu X D, Song X F, Li D S, Liu J G, Zhang P B, Chen X S. J Bionic Eng, 2012, 9: 224
37. [37]
  [37] Chen D, Qu Z P, Sun Y H, Wang Y. Colloid Surf A, 2014, 441: 433
38. [38]
  [38] Huo Q S, Margolese D I, Stucky G D. Chem Mater, 1996, 8: 1147
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