Citation: Zujin Yang, Hongbing Ji. Synergistic effect of hydrogen bonding mediated selective synthesis of benzaldehyde in water[J]. Chinese Journal of Catalysis, ;2014, 35(4): 590-598. doi: 10.1016/S1872-2067(14)60056-5 shu

Synergistic effect of hydrogen bonding mediated selective synthesis of benzaldehyde in water

Zujin Yang ,
Hongbing Ji ^,

1.
School of Chemistry and Chemical Engineering, Key Laboratory of Low-carbon Chemistry &Energy Conservation of Guangdong Province, Sun Yat-sen University, Guangzhou 510275, Guangdong, China

Corresponding author: Hongbing Ji,
Received Date: 23 November 2013
Available Online: 3 January 2014
Fund Project: 国家自然科学基金(21376279, 21176268, 21036009) (21376279, 21176268, 21036009)广东省重大科技专项(2012A080103005) (2012A080103005)广东省部产学研结合项目(2011B090400439). (2011B090400439)

β-cyclodextrin-functionalized cellulose was prepared from cellulose and β-cyclodextrin crosslinked with epichlorohydrin. The supramolecular polymer has been used as a heterogeneous catalyst for the synthesis of benzaldehyde under mild reaction conditions with high activity and yield. The catalyst was easily recovered and reused without significant activity loss. The β-cyclodextrin in the polymer formed host-guest complexes with cinnamaldehyde via noncovalent bonding. In addition, multiple interactions were observed between β-cyclodextrin and the substrate via intermolecular O-H…O hydrogen bonding. The significant promotion for the catalytic performance could be attributed to the synergistic effects of hydrogen bonding.
- β-cyclodextrin-functionalized cellulose,
- Hydrogen bonding,
- Synergistic effect,
- Cinnamaldehyde oxidation,
- Benzaldehyde
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