Citation: LI Bing, TIAN Peng, QI Yue, ZHANG Lin, XU Shutao, SU Xiong, FAN Dong, LIU Zhongmin. Study of crystallization process of SAPO-11 molecular sieve[J]. Chinese Journal of Catalysis, ;2013, 34(3): 593-603. doi: 10.1016/S1872-2067(12)60542-7 shu

Study of crystallization process of SAPO-11 molecular sieve

LI Bing ^a ,
TIAN Peng ^a ,
QI Yue ^a ,
ZHANG Lin ^a ,
XU Shutao ^a ,
SU Xiong ^a,b ,
FAN Dong ^a,b ,
LIU Zhongmin ^a,,

1.
a Dalian National Laboratory for Clean Energy, National Engineering Laboratory for Methanol-to-Olefins, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: LIU Zhongmin,
Received Date: 21 November 2012
Available Online: 30 December 2012

The crystallization process of SAPO-11 was studied using a combination of X-ray diffraction, scanning electron microscopy, X-ray fluorescence, nuclear magnetic resonance, and X-ray photoelectron spectroscopy. In the initial stage of crystallization, SAPO-11 was formed along with an unknown crystalline material composed of Si-P-Al. As crystallization evolved, the crystalline material dissolved. The SAPO-11 formation rate increased greatly, which is characteristic of fast crystallization. After 2.33 h, the relative crystallinity of SAPO-11 reached ~100% and remained at a high level until crystallization was complete. Si was incorporated into the SAPO-11 framework from the initial stage of crystallization. The Si content of the solid samples increased with crystallization time. Most of the Si atoms existed as Si islands in the SAPO-11 framework, resulting in the presence of multiple coordination environments, i.e., Si(nAl, (4-n)Si), n=0-4. X-ray photoelectron spectroscopy analysis revealed Si enrichment on the external surfaces of the SAPO-11 crystals. Based on the experimental results, the distribution of Si in the crystals is not uniform, showing an increasing trend from the core to the surface.
- SAPO-11 molecular sieve,
- Characterization,
- Crystallization process,
- Silicon distribution
1. [1]
  [1] Lok B M, Messina C A, Patton R L, Gajek R T, Cannan T R, Flanigen E M. USPatent4440871. 1984
2. [2]
  [2] Zhang Sh Zh, Chen Sh L, Dong P, Yuan G M, Xu K Q. Appl Catal A, 2007, 332: 46
3. [3]
  [3] Luo H J, Wu H J, Wu H Y, Zhang Y Y, Wang Y J. Ind Catal (罗洪君,吴红姣,吴红玉,张莹莹,汪颖军. 工业催化), 2011, 19(1): 16
4. [4]
  [4] Wang Y J,Li X H,Liu Ch Sh, Jin L L.Ind Catal (汪颖军,李小辉,刘成双,靳丽丽. 工业催化),2010,18(3): 1
5. [5]
  [5] Tian Zh J, Liang D B, Lin L W. Chin J Catal (田志坚, 梁东白, 林励吾. 催化学报), 2009, 30: 705
6. [6]
  [6] Wang Zh M, Yan Z F. J Fuel Chem Technol (汪哲明, 阎子峰. 燃料化学学报), 2003, 31: 360
7. [7]
  [7] Liu Y M, Zhang F M, Shu X T. Acta Petrol Sin (Petrol Proc Sect) (刘月明, 张凤美, 舒兴田. 石油学报(石油加工)), 2002, 18(6): 26
8. [8]
  [8] Liu P, Ren J, Sun Y H. Acta Petrol Sin (Petrol Proc Sect) (刘平, 任杰, 孙予罕. 石油学报(石油加工)), 2008, 24(4): 388
9. [9]
  [9] Zhang Sh Zh, Chen Sh L, Dong P, Jing X J, Jiang K. Chin J Catal (张胜振, 陈胜利, 董鹏, 井秀娟, 姜凯. 催化学报), 2006, 27: 868
10. [10]
  [10] Gharibeh M, Tompsett G A, Conner W C. Top Catal, 2008, 49: 157
11. [11]
  [11] Sinha A K, Seelan S. Appl Catal A, 2004, 270: 245
12. [12]
  [12] Chen B H, Huang Y N. J Phys Chem C, 2007, 111: 15236
13. [13]
  [13] Song Ch M, Feng Y, Ma L L. Microporous Mesoporous Mater, 2012, 147: 205
14. [14]
  [14] Chen B H, Huang Y N. J Am Chem Soc, 2006, 128: 6437
15. [15]
  [15] Zhang B, Xu J, Fan F T, Guo Q, Tong X Q, Yan W F, Yu J H, Deng F, Li C, Xu R R. Microporous Mesoporous Maters, 2012, 147: 212
16. [16]
  [16] Cheng T, Xu J, Li X, Li Y, Zhang B, Yan W F, Yu J H, Sun H, Deng F, Xu R R. Microporous Mesoporous Mater, 2012, 152: 190
17. [17]
  [17] Liu G Y, Tian P, Zhang Y, Li J Zh, Xu L, Meng Sh H, Liu Zh M. Microporous Mesoporous Mater, 2008, 114: 416
18. [18]
  [18] Huang Y N, Richer R, Kirby C W. JPhys Chem B, 2003, 107: 1326
19. [19]
  [19] Zhang L, Bates J, Chen D H, Nie H Y, Huang Y N. J Phys Chem C, 2011, 115: 22309
20. [20]
  [20] Lutz W, Kurzhals R, Sauerbeck S, Toufar H, Buhl J Chr, Gesing T, Altenburg W, Jäger Chr. Microporous Mesoporous Mater, 2010, 132: 31
21. [21]
  [21] Yan Zh M, Chen B H, Huang Y N. Solid State Nucl Magn Reson, 2009, 35: 49
22. [22]
  [22] Borade R B, Clearfield A. J Mol Catal, 1994, 88: 249
23. [23]
  [23] Wang Sh F, Wang Y J, Gao Y, Zhao X Q. Chin J Catal (王淑芳, 王延吉, 高扬, 赵新强. 催化学报), 2010, 31: 637
24. [24]
  [24] Blasco T, Chica A, Corma A, Murphy W J, Agúndez-Rodriguez J, Pérez-Pariente J. J Catal, 2006, 242: 153
25. [25]
  [25] Barthomeuf D. J Phys Chem, 1993, 97: 10092
26. [26]
  [26] Shen W L, Li X, Wei Y X, Tian P, Deng F, Han X W, Bao X H. Microporous Mesoporous Mater, 2012, 158: 19
27. [27]
  [27] Kikhtyanin O V, Toktarev A V, Ayupov A B, Echevsky G V. Appl Catal A, 2010, 378: 96
28. [28]
  [28] Akolekar D B, Bhargava S K, Gorman J, Paterson P. Colloids Surf A, 1999, 146: 375
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