Citation: SUI Minghao, SHE Lei, SHENG Li, WEI Jinjie, ZHANG Lingdian, HUANG Shuhang. Ordered mesoporous manganese oxide as catalyst for hydrogen peroxide oxidation of norfloxacin in water[J]. Chinese Journal of Catalysis, ;2013, 34(3): 536-541. doi: 10.1016/S1872-2067(11)60492-0 shu

Ordered mesoporous manganese oxide as catalyst for hydrogen peroxide oxidation of norfloxacin in water

1.
State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China

Corresponding author: SUI Minghao,
Received Date: 31 August 2012
Available Online: 22 November 2012
Fund Project: 国家自然科学基金(50708067, 51078281, 51278351) (50708067, 51078281, 51278351) 百篇优秀博士论文项目(2007B48) (2007B48) 国家科技重大专项(2012ZX07408001) (2012ZX07408001)中央高校基本科研业务费专项基金(0400219192). (0400219192)

Ordered mesoporous manganese oxide (om-MnO_x) was prepared and used in oxidation by hydrogen peroxide of norfloxacin (NFX). The om-MnO_x was prepared using a hard template method. The catalytic activity of om-MnO_x was investigated by evaluating the changes in degradation efficiency and antibacterial activity of NFX. om-MnO_x exhibited significant catalytic activity for the degradation of NFX in water by hydrogen peroxide. Lower pH conditions favored the catalytic activity of om-MnO_x/hydrogen peroxide. The presence of om-MnO_x achieved a greater reduction in the antibacterial ability of NFX than that was obtained with hydrogen peroxide alone. The inhibiting effect of t-butanol indicated that om-MnO_x enhanced the generation of hydroxyl radicals. Byproducts from NFX were detected during the om-MnO_x-catalyzed hydrogen peroxide process, and possible reaction pathways were proposed.
- Ordered mesoporous material,
- Manganese oxide,
- Hydrogen peroxide,
- Oxidation,
- Norfloxacin
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沈阳化工大学材料科学与工程学院沈阳 110142