Citation: MA Hengchang, BAO Zhikang, HAN Guobin, YANG Ningning, XU Yufei, YANG Zengming, CAO Wei, MA Yuan. Nanoparticulate palladium catalyst stabilized by supported on feather keratin for Suzuki coupling reaction[J]. Chinese Journal of Catalysis, ;2013, 34(3): 578-584. doi: 10.1016/S1872-2067(11)60472-5 shu

Nanoparticulate palladium catalyst stabilized by supported on feather keratin for Suzuki coupling reaction

1.
Key Laboratory of Polymer Materials of Gansu Province, Key Laboratory of Eco-Environment-Related Polymer Materials Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, Gansu, China

Corresponding author: MA Hengchang,
Received Date: 30 September 2012
Available Online: 23 October 2012
Fund Project: 国家自然科学基金(21202133). (21202133)

Palladium nanoparticlessupported in afeather keratin matrix were efficient catalyst for the coupling reactions of aryl bromides with arylboronic acid in aqueous medium under mild reaction conditions. The biopolymer-based catalyst demonstrated excellent activity for substrates with a wide range of functional groups. The product biaryls were precipitated from the reaction mixture with good to excellent yields and purities. The catalyst was recovered from the reaction solution easily by simple filtration, and can be reused at least seven times.
- Suzuki reaction,
- Nanoparticle,
- Feather keratin,
- Hydrophobic effect,
- Water
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