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Citation: DENG Wen-Ping, XU Gang, WAN Lei, LIU An-Wen, GAO Bo, DU Jun-He, HU Shui-Ming, CHEN Yang. Apparatus for High-Resolution Solid Hydrogen Matrix Isolation Spectroscopy and Its Application[J]. Acta Physico-Chimica Sinica, ;2008, 24(08): 1329-1334. doi: 10.1016/S1872-1508(08)60054-6 shu

Apparatus for High-Resolution Solid Hydrogen Matrix Isolation Spectroscopy and Its Application

1.
Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, P. R. China

Received Date: 10 March 2008
Available Online: 4 June 2008

Apparatus integrating a Fourier transform-infrared (FT-IR) spectrometer and a mid-infrared difference frequency generation (DFG) laser pectrometer was built for the study of the matrix isolation spectrumin solid molecular hydrogen. A 3-cm-long molecular hydrogen crystal was grown in a liquid-helium Dewar and its infrared absorption spectrum in the 1-5 μm region was recorded to test the system. The W0(0) (v=0→0, J=6→0) line around 2410 cm-1 of solid hydrogen was investigated with the DFG laser spectroscopy. High-resolution matrix isolation spectrum of CO2 co-deposited with hydrogen on a BaF2 cold plate at liquid-heliumtemperature was studied.
- Hydrogen molecule,
- Matrix isolation,
- Fourier transform-infrared spectroscopy,
- Laser difference frequency generation,
- Carbon dioxide
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