Citation:
WANG Zhu-Yi, CHEN Cheng, FENG Cai-Hui, WANG Jin-Xing, ZOU Bo, ZHAO Meng, WU Feng-Qing. Synthesis, Characterization and Humidity Sensitive Properties of Nanocrystalline LaCoxFe1-xO3[J]. Acta Physico-Chimica Sinica,
;2008, 24(03): 375-378.
doi:
10.1016/S1872-1508(08)60017-0
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The nanocrystalline LaCoxFe1 -xO3 with different concentrations of Co was prepared by polyethylene glycol (PEG) sol-gel method and characterized by differential thermal analysis and thermal gravimetric analysis (DTA-TGA), X-ray diffraction (XRD), and scanning electron microscope (SEM). It was found that the crystal structure of perovskite-type could be obtained at 600 ℃, and the concentration of Co had significant effects on the solid-state reaction and the average particle size of the obtained nanocrystals. Furthermore, the humidity-sensitive properties of nanocrystalline LaCoxFe1 -xO3 were investigated, and it was found that LaCo0.3Fe0.7O3 exhibited higher sensitivity to humidity compared with other samples. The addition of Na2CO3 improved the humidity-sensitive properties of this sample, and made its response to humidity od in the whole humidity range of 11%-95%relative humidity (RH).
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Keywords:
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Perovskite
, - LaCoxFe1-xO3,
- Humidity sensitive property
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