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Citation: YANG Zi-Liang, YANG Si-Hai, LI Guo-Bao, LIN Jian-Hua. Synthesis, Structure and Thermal Properties of [HN(C₂H₅)₃][B₅O₆(OH)₄][J]. Acta Physico-Chimica Sinica, ;2007, 23(03): 285-288. doi: 10.1016/S1872-1508(07)60020-5 shu

Synthesis, Structure and Thermal Properties of [HN(C₂H₅)₃][B₅O₆(OH)₄]

1.
Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 21 August 2006
Available Online: 7 March 2007

Triethylamine pentaborate, [HN(C2H5)3][B5O6(OH)4] (1), was hydrothermally synthesized and characterized by single crystal X-ray diffraction, FTIR, elemental analysis, and thermogravimetric analysis. Compound 1 crystallized in the monoclinic system, space group P21/c with a=1.0036(2) nm, b=1.1353(2) nm, c=1.4843(3) nm, and β=106.54(3)°. It consisted of isolated borate polyanion [B5O6(OH)4]- and triethylamine cation [HN(C2H5)3]+. The anionic units, [B5O6(OH)4]-, were linked by hydrogen bonds to form a 3D supramolecular network containing large channels, in which the templating [HN(C2H5)3]+ cations were located.
- Crystal structure,
- Triethylamine pentaborate,
- Hydrothermal reaction
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Synthesis, Structure and Thermal Properties of [HN(C2H5)3][B5O6(OH)4]

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Structure and Thermal Properties of [HN(C₂H₅)₃][B₅O₆(OH)₄]