Citation: Si-Qi Teng, Zhi-Guo Jiang, Zhao-Bin Qiu. Crystallization Behavior and Dynamic Mechanical Properties of Poly(ε-caprolactone)/Octaisobutyl-Polyhedral Oligomeric Silsesquioxanes Composites Prepared via Different Methods[J]. Chinese Journal of Polymer Science, ;2020, 38(2): 158-163. doi: 10.1007/s10118-020-2338-5 shu

Crystallization Behavior and Dynamic Mechanical Properties of Poly(ε-caprolactone)/Octaisobutyl-Polyhedral Oligomeric Silsesquioxanes Composites Prepared via Different Methods

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Zhi-Guo Jiang, jiangzg@mail.buct.edu.cn Zhao-Bin Qiu, qiuzb@mail.buct.edu.cn
Received Date: 28 April 2019
Revised Date: 25 June 2019
Available Online: 10 October 2019

Two octaisobutyl-polyhedral oligomeric silsesquioxanes (oib-POSS) reinforced biodegradable poly(ε-caprolactone) (PCL) composites were prepared via two different methods, i.e., melt compounding and solution casting, which were named as mPCL/oib-POSS and sPCL/oib-POSS, respectively, in this work. Oib-POSS dispersed finely in both composites; moreover, oib-POSS aggregates were larger in mPCL/oib-POSS than in sPCL/oib-POSS. Despite the different preparation methods, oib-POSS obviously promoted the crystallization of PCL, especially in sPCL/oib-POSS, but did not modify the crystal structure of PCL. The storage moduli of PCL were improved significantly in both composites. PCL/oib-POSS composites with enhanced crystallization behavior and improved dynamic mechanical properties were successfully prepared through both methods; moreover, the solution casting method was more effective than the melt compounding method.
- Poly(ε-caprolactone),
- POSS,
- Crystallization
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