Citation: Meng-Qi Du, Yu-Zheng Peng, Yuan-Chi Ma, Li Yang, Yuan-Lin Zhou, Fan-Kun Zeng, Xiang-Ke Wang, Man-Ling Song, Guan-Jun Chang. Selective Carbon Dioxide Capture in Antifouling Indole-based Microporous Organic Polymers[J]. Chinese Journal of Polymer Science, ;2020, 38(2): 187-194. doi: 10.1007/s10118-019-2326-9 shu

Selective Carbon Dioxide Capture in Antifouling Indole-based Microporous Organic Polymers

Meng-Qi Du ^a,† ,
Yu-Zheng Peng ^a,† ,
Yuan-Chi Ma ^b,† ,
Li Yang ^a,b,, ,
Yuan-Lin Zhou ^a,, ,
Fan-Kun Zeng ^a,, ,
Xiang-Ke Wang ^a ,
Man-Ling Song ^a ,
Guan-Jun Chang ^a,b,,

a.
State Key Laboratory of Environment-friendly Energy Materials, School of Material Science and Engineering, School of Life Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China
b.
Department of Chemical and Biomolecular Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States

Corresponding author: Li Yang, yanglichem628@126.com Yuan-Lin Zhou, zhouyuanlin@swust.edu.cn Fan-Kun Zeng, fkzeng920924@163.com Guan-Jun Chang, gjchang@mail.ustc.edu.cn
Received Date: 25 May 2019
Revised Date: 29 June 2019
Available Online: 29 September 2019

Intermolecular synergistic adsorption of indole and carbonyl groups induced by intermolecular hydrogen bonding makes microporous organic polymer (PTICBL) exhibit high CO₂ uptake capacity (5.3 mmol·g⁻¹ at 273 K) and selectivities (CO₂/CH₄ = 53, CO₂/N₂ = 107 at 273 K). In addition, we find that indole units in the PTICBL networks inhibit the attachment of bacteria (E. coil and S. aureus) on the surface of PTICBL and extend its service life in CO₂ capture.
- CO₂ capture,
- Synergistic adsorption,
- Antifouling,
- Indole,
- Microporous organic polymer
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