Citation: Cheng-Jian Zhang, Xing-Hong Zhang. Recent Progress on COS-derived Polymers[J]. Chinese Journal of Polymer Science, ;2019, 37(10): 951-958. doi: 10.1007/s10118-019-2288-y shu

Recent Progress on COS-derived Polymers

Cheng-Jian Zhang ,
Xing-Hong Zhang ^,

Key Laboratory of Macromolecular Synthesis and Functionalization (Ministry of Education), Department of Polymer Science & Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Xing-Hong Zhang, xhzhang@zju.edu.cn
Received Date: 28 March 2019
Revised Date: 23 April 2019
Available Online: 1 July 2019

The synthesis of sulfur-containing polymer, a very promising functional material, has made a great progress in the past several years. This review is focused on the very recent advances in poly(monothiocarbonate)s derived from carbonyl sulfide (COS) and epoxides including biomass-derived epoxides. Of significance, metal-free catalyst systems, including triethyl borane/Lewis base pair and thiourea/Lewis base pair are developed for the alternating copolymerization of COS with epoxides. Thereof, the thiourea/Lewis base pair is highly active to the copolymerization of COS with epoxide in a living manner. Moreover, a series of crystalline poly(monothiocarbonate)s are presented, including the copolymers derived from COS with oxetane, ethylene oxide, enantiopure epichlorohydrin, and achiral meso-epoxides via enantioselective copolymerization. Based on these COS/epoxide copolymerization process, a variety of COS-based block copolymers with well-defined structure are presented.
- Carbonyl sulfide,
- Epoxide,
- Copolymerization,
- Poly(monothiocarbonate)
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