Citation: Qi Yu, Ya-Long Wang, Ze-Qiang Chen, Peng-Ju Zhao, Cheng Fan, Chong Li, Ming-Qiang Zhu. Geminal Cross Coupling (GCC) Reaction for AIE Materials[J]. Chinese Journal of Polymer Science, ;2019, 37(4): 327-339. doi: 10.1007/s10118-019-2207-2 shu

Geminal Cross Coupling (GCC) Reaction for AIE Materials

Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: Chong Li, chongli@hust.edu.cn Ming-Qiang Zhu, mqzhu@hust.edu.cn
Received Date: 30 October 2018
Revised Date: 6 December 2018
Accepted Date: 9 December 2018
Available Online: 11 January 2019

Tetraphenylethylene (TPE) derivatives are typical aggregation-induced emission (AIE) molecules, which have been widely investigated and applicated. The Rathore’s procedures and McMurry reaction are the two frequently used methods for synthesizing the TPE derivatives. The complex processes and low tolerance of active function groups make the TPE with limited structures and properties in some degree. Very recently, a novel strategy, named geminal cross coupling (GCC) reaction, is developed for designing and synthesizing various topological small molecules and polymers with rich optical properties beyond simple TPE compounds, and becomes a powerful synthesis method to AIE materials. This review overviews the current progresses of AIE molecules and polymers prepared by GCC as well as their applications. We believe that GCC reaction will have a bright future in the development of the next generation of tetraarylethylene (TAE)-kind AIE materials.
- GCC reaction,
- AIE,
- Tetraarylethylene,
- Conjugated polymer,
- Imaging
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沈阳化工大学材料科学与工程学院沈阳 110142