Citation: Jiang-bo Lv, Jing-zhi Ma, Kang Cheng, Chang Chen, Jiang-huai Hu, Ke Zeng, Gang Yang. Insights into Phthalonitrile/Epoxy Blends Modification System from Non-competitive Cure System Based on Alicyclic Anhydride[J]. Chinese Journal of Polymer Science, ;2017, 35(12): 1561-1571. doi: 10.1007/s10118-017-1992-8 shu

Insights into Phthalonitrile/Epoxy Blends Modification System from Non-competitive Cure System Based on Alicyclic Anhydride

State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China

Corresponding author: Ke Zeng, zk_ican@sina.com Gang Yang, yanggang65420@163.com
Received Date: 15 May 2017
Accepted Date: 12 June 2017

Fund Project: the National Natural Science Foundation of China 51173114the National Natural Science Foundation of China 51203098

A series of polymer blends were prepared from 1, 3-bis(3, 4-dicyanophenoxy)benzene (3BOCN) and epoxy resin with methyl tetrahydrophthalic anhydride as curing agent. The curing behavior and curing kinetics of the blends were studied by differential scanning calorimetry. The apparent activation energy of the blends with various contents of 3BOCN was higher than that of the blends without 3BOCN. A model experiment suggested that there is no obvious reaction between phthalonitrile and epoxy. The thermal and mechanical properties of the polymer blends were evaluated. The polymer blends exhibit high storage modulus and char yield compared with the neat epoxy. The polymer blends show ductile fracture morphology by scanning electron microscopy (SEM) images.
- Polymer blends,
- Phthalonitrile,
- Epoxy resin,
- Non-competitive
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