Citation: Yi-hu Song, Ling-bin Zeng, Qiang Zheng. Understanding the Reinforcement and Dissipation of Natural Rubber Compounds Filled with Hybrid Filler Composed of Carbon Black and Silica[J]. Chinese Journal of Polymer Science, ;2017, 35(11): 1436-1446. doi: 10.1007/s10118-017-1987-5 shu

Understanding the Reinforcement and Dissipation of Natural Rubber Compounds Filled with Hybrid Filler Composed of Carbon Black and Silica

a.
Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Zhejiang University, Hangzhou 310027, China
b.
Shanghai Aerospace System Engineering Institute, Shanghai 201110, China

Corresponding author: Yi-hu Song, s_yh0411@zju.edu.cn
Received Date: 13 April 2017
Revised Date: 16 May 2017
Accepted Date: 27 May 2017

Fund Project: the Major Projects of Science and Technology Plan of Guizhou Province (2013) 6016the National Natural Science Foundation of China 51373149the Natural Science Foundation of Zhejiang Province R14E030003the SAST Innovation Fund yy-F08052015100029the National Natural Science Foundation of China 51333004the National Natural Science Foundation of China 51573157

The performance of reinforced rubber compounds depends on the filler composition while the reinforcement and dissipation mechanisms still remain unclear. Herein linear and nonlinear dynamic rheological responses of carbon black/silica hybrid filler filling nature rubber compounds are investigated. The rheological contributions of dynamically retarded bulk phase and filler network are revealed to be crucial at high and low frequencies, respectively, and the bulk phase is shown to be of vital importance for the occurrence of nonlinear Payne effect at mediate frequencies. A framework for simultaneously solving reinforcement and dissipation varying with filler composition and content is suggested, providing a new perspective in understanding the filling effect for manufacturing high-performance rubber materials.
- Filling,
- Reinforcement,
- Dissipation,
- Rubber compounds,
- Time-concentration superpositioning principle
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