Citation: Ruo-lin Wang, Rui Qu, Yan Zhai, Chen Jing, Ang Li, Ying-li An, Lin-qi Shi. Enhanced Electron Transfer Ability via Coordination in Block Copolymer/Porphyrin/Fullerene Micelle[J]. Chinese Journal of Polymer Science, ;2017, 35(11): 1328-1341. doi: 10.1007/s10118-017-1973-y shu

Enhanced Electron Transfer Ability via Coordination in Block Copolymer/Porphyrin/Fullerene Micelle

State Key Laboratory of Medicinal Chemical Biology, Key Laboratory of Functional Polymer Materials, Ministry of Education, Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Institute of Polymer Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Lin-qi Shi, shilinqi@nankai.edu.cn
Received Date: 14 April 2017
Revised Date: 2 May 2017
Accepted Date: 8 May 2017

Fund Project: the National Natural Science Foundation of China 51503104the National Natural Science Foundation of China 91527306the Natural Science Foundation of Tianjin 16JCQNJC03000the National Natural Science Foundation of China 21620102005the National Natural Science Foundation of China 51390483the Natural Science Foundation of Tianjin 16JCQNJC02500the National Natural Science Foundation of China 51603231

Inspired by structures of antenna-reaction centers in photosynthesis, the complex micelle was prepared from zinc tetra-phenyl porphyrin (ZnTPP), fullerene derivative (PyC₆₀) and poly(ethylene glycol)-block-poly(ε-caprolactone) (PEG-b-PCL). The core-shell structure made the hydrophobic donor-acceptor system work in aqueous. In micellar core, coordination interaction occurred between ZnTPP and PyC₆₀ molecules which ensured the enhanced energy migration from the donor to the acceptor. The enhanced interaction between porphyrin and fullerene was confirmed by absorption, steady-state fluorescence and transient fluorescence. The generation of singlet oxygen and superoxide radical was detected by iodide method and reduction of nitro blue tetrazolium, respectively, which confirmed that electron transfer reaction in the complex micellar core occurred. Moreover, the complex micelle exhibited effective electron transfer performance in photodebromination of 2, 3-dibromo-3-phenylpropionic acid. The complex micellar structure endowed the donor-acceptor system with improved stability under irradiation. This strategy could be helpful for designing new electron transfer platform and artificial photosynthetic system.
- Porphyrin,
- Fullerene,
- Micelle,
- Coordination,
- Electron transfer
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