Citation: Jie-huan Chen, Shi-da Yang, Wen-qing Liu, Wei-fei Fu, Hong-zheng Chen. Improved Photovoltaic Performance from High Quality Perovskite Thin Film Grown with the Assistance of PC₇₁BM[J]. Chinese Journal of Polymer Science, ;2017, 35(2): 309-316. doi: 10.1007/s10118-017-1891-z shu

Improved Photovoltaic Performance from High Quality Perovskite Thin Film Grown with the Assistance of PC₇₁BM

Key Laboratory of Macromolecular Synthesis and Functionalization, Ministry of Education, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Hong-zheng Chen, hzchen@zju.edu.cn
Received Date: 21 October 2016
Revised Date: 31 October 2016
Accepted Date: 2 November 2016

Fund Project: the Major State Basic Research Development Program 2014CB643503the National Natural Science Foundation of China 51620105006the Program for Innovative Research Team in University of Ministry of Education of China IRT13R54

The strategy of sequentially spin-coating a perovskite film from the perovskite precursor and an electron transporting layer of[6, 6]-phenyl-C₇₁-butyric acid methyl ester (PC₇₁BM) is developed to simplify the fabrication procedure of perovskite solar cells. X-ray diffraction and scanning electron microscopy indicate that PC₇₁BM film on perovskite layer can retard the evaporation of dimethyl sulfoxide (DMSO) efficiently, thus prolonging the transformation of intermediate phase to perovskite crystals, leading to a high quality perovskite thin film. The solar cells with the structure of indium tin oxides (ITO)/poly (3, 4-ethylenedioxythiophene):poly (styrenesulfonate) (PEDOT:PSS)/CH₃NH₃PbI₃/PC₇₁BM/bathocuproine (BCP)/Ag made from this simplified method exhibit a higher efficiency (12.68%) than those from the conventional one-step method (9.49%).
- Perovskite solar cells,
- Simplified preparation process,
- Crystallization
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Improved Photovoltaic Performance from High Quality Perovskite Thin Film Grown with the Assistance of PC71BM

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Improved Photovoltaic Performance from High Quality Perovskite Thin Film Grown with the Assistance of PC₇₁BM