Citation: Ru-yan Zhao, Chuan-dong Dou, Jun Liu, Li-xiang Wang. An Alternating Polymer of Two Building Blocks Based on B←N Unit: Non-fullerene Acceptor for Organic Photovoltaics[J]. Chinese Journal of Polymer Science, ;2017, 35(2): 198-206. doi: 10.1007/s10118-017-1878-9 shu

An Alternating Polymer of Two Building Blocks Based on B←N Unit: Non-fullerene Acceptor for Organic Photovoltaics

Ru-yan Zhao ^a,b ,
Chuan-dong Dou ^a,, ,
Jun Liu ^a,, ,
Li-xiang Wang ^a

a.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Chuan-dong Dou, chuandong.dou@ciac.ac.cn Jun Liu, liujun@ciac.ac.cn
Received Date: 15 July 2016
Revised Date: 3 August 2016
Accepted Date: 4 August 2016

Fund Project: the National Natural Science Foundation of China 51373165the National Natural Science Foundation of China 21404099financially supported by the 973 Program 2014CB643504the State Key Laboratory of Supramolecular Structure and Materials in Jilin University sklssm201608the National Natural Science Foundation of China 21574129the “Thousand Talents Program” of China, the Strategic Priority Research Program of the Chinese Academy of Sciences XDB12010200

B←N coordination bond can be used to develop polymer electron acceptors for efficient all-polymer solar cells (all-PSCs). Here, we report a new alternating conjugated polymer containing two building blocks based on B←N unit. The polymer exhibits strong light absorption in the visible range, low-lying LUMO/HOMO energy levels and moderate electron mobility. The resulting all-PSC devices exhibit power conversion efficiencies of 1.50%-2.47%.
- All-polymer solar cells,
- Polymer acceptor,
- Boron,
- B←N coordination bond
1. [1]
  Kim, T., Kim, J.H., Kang, T.E., Lee, C., Kang, H., Shin, M., Wang, C., Ma, B., Jeong, U., Kim, T.S. and Kim, B.J., Nat. Commun., 2015, 6:8547 doi: 10.1038/ncomms9547
2. [2]
  Facchetti, A., Mater. Today, 2013, 16:123 doi: 10.1016/j.mattod.2013.04.005
3. [3]
  Yu, G., Gao, J., Hummelen, J.C., Wudl, F. and Heeger, A.J., Science, 1995, 270:1789 doi: 10.1126/science.270.5243.1789
4. [4]
  Lin, Y. and Zhan, X., Acc. Chem. Res., 2016, 49:175 doi: 10.1021/acs.accounts.5b00363
5. [5]
  Gao, L., Zhang, Z.G., Xue, L., Min, J., Zhang, J., Wei, Z. and Li, Y., Adv. Mater., 2016, 28:1884 doi: 10.1002/adma.201504629
6. [6]
  Song, H., Tong, H., Xie, Z., Wang, L. and Wang, F., Chinese J. Polym. Sci., 2013, 31:1117 doi: 10.1007/s10118-013-1302-z
7. [7]
  Lu, L., Zheng, T., Wu, Q., Schneider, A.M., Zhao, D. and Yu, L., Chem. Rev., 2015, 115:12666 doi: 10.1021/acs.chemrev.5b00098
8. [8]
  Zhang, S., Ye, L., Zhao, W., Tang, B., Wang, Q. and Hou, J., Sci. China Chem., 2015, 58:248 doi: 10.1007/s11426-014-5273-x
9. [9]
  Lu, Z., Li, C., Du, C., Gong, X. and Bo, Z., Chinese J. Polym. Sci., 2013, 31:901 doi: 10.1007/s10118-013-1275-y
10. [10]
  Liao, X.F., Wang, J., Chen, S.Y., Chen, L. and Chen, Y.W., Chinese J. Polym. Sci., 2016, 34:491 doi: 10.1007/s10118-016-1761-0
11. [11]
  Ye, L., Jiao, X., Zhou, M., Zhang, S., Yao, H., Zhao, W., Xia, A., Ade, H. and Hou, J., Adv. Mater., 2015, 27:6046 doi: 10.1002/adma.201503218
12. [12]
  Zhou, N., Lin, H., Lou, S.J., Yu, X., Guo, P., Manley, E.F., Loser, S., Hartnett, P., Huang, H., Wasielewski, M.R., Chen, L.X., Chang, R.P.H., Facchetti, A. and Marks, T.J., Adv. Energy Mater., 2014, 4:1300785 doi: 10.1002/aenm.201300785
13. [13]
  Mu, C., Liu, P., Ma, W., Jiang, K., Zhao, J.B., Zhang, K., Chen, Z.H., Wei, Z.H., Yi, Y., Wang, J.N., Yang, S.H., Huang, F., Faccheti, A., Ade, H. and Yan, H., Adv. Mater., 2014, 26:7224 doi: 10.1002/adma.v26.42
14. [14]
  Li, W.W., Roelofs, W.S.C., Turbiez, M., Wienk, M.M. and Janssen, R.A.J., Adv. Mater., 2014, 20:3304
15. [15]
  Schubert, M., Collins, B.A., Mangold, H., Howard, I.A., Schindler, W., Vandewal, K., Roland, S., Behrends, J., Kraffert, F., Steyrleuthner, R., Chen, Z., Fostiropoulos, K., Bittl, R., Salleo, A., Facchetti, A., Laquai, F., Ade, H.W. and Neher, D., Adv. Funct. Mater., 2014, 24:4068 doi: 10.1002/adfm.201304216
16. [16]
  Hwang, Y.J., Earmme, T., Courtright, B.A.E., Eberle, F.N. and Jenekhe, S.A., J. Am. Chem. Soc., 2015, 137:4424 doi: 10.1021/ja513260w
17. [17]
  Kang, H., Uddin, M.A., Lee, C., Kim, K.H., Nguyen, T.L., Lee, W., Li, Y.X., Wang, C., Woo, H.Y. and Kim, B., J. Am. Chem. Soc., 2015, 137:2359 doi: 10.1021/ja5123182
18. [18]
  Cheng, P., Ye, L., Zhao, X., Hou, J., Li, Y. and Zhan, X., Energy Environ. Sci., 2014, 7:1351 doi: 10.1039/C3EE43041C
19. [19]
  Zhan, X., Tan, Z., Domercq, B., An, Z., Zhang, X., Barlow, S., Li, Y., Zhu, D., Kippelen, B. and Marder, S.R., J. Am. Chem. Soc., 2007, 129:7246 doi: 10.1021/ja071760d
20. [20]
  Zhou, Y., Kurosawa, T., Ma, W., Guo, Y., Fang, L., Vandewal, K., Diao, Y., Wang, C., Yan, Q., Reinspach, J., Mei, J., Appleton, A.L., Koleilat, G.I., Gao, Y., Mannsfeld, S.C.B., Salleo, A., Ade, H., Zhao, D. and Bao, Z., Adv. Mater., 2014, 26:3767 doi: 10.1002/adma.v26.22
21. [21]
  Dou, C., Saito, S., Matsuo, K., Hisaki, I. and Yamaguchi, S., Angew. Chem. Int. Ed., 2012, 51:12206 doi: 10.1002/anie.v51.49
22. [22]
  Rao, Y.L. and Wang, S., Inorg. Chem., 2011, 50:12263 doi: 10.1021/ic200658v
23. [23]
  Tanaka, K. and Chujo, Y., Macromol. Rapid Commun., 2012, 33:1235 doi: 10.1002/marc.v33.15
24. [24]
  Jäkle, F., Chem. Rev., 2010, 110:3985 doi: 10.1021/cr100026f
25. [25]
  Yamaguchi, S. and Wakamiya, A., Pure Appl. Chem., 2006, 78:1413
26. [26]
  Wang, X., Zhuang, F., Wang, R., Wang, X., Cao, X., Wang, J. and Pei, J., J. Am. Chem. Soc., 2014, 136:3764 doi: 10.1021/ja500117z
27. [27]
  Wang, X.Y., Lin, H.R., Lei, T., Yang, D.C., Zhuang, F.D., Wang, J.Y., Yuan, S.C. and Pei, J., Angew. Chem. Int. Ed., 2013, 52:3117 doi: 10.1002/anie.201209706
28. [28]
  Li, D., Zhang, H. and Wang, Y., Chem. Soc. Rev., 2013, 42:8416 doi: 10.1039/c3cs60170f
29. [29]
  Zalar, P., Henson, Z.B., Welch, G.C., Bazan, G.C. and Nguyen, T.Q., Angew. Chem. Int. Ed., 2012, 51:7495 doi: 10.1002/anie.201202570
30. [30]
  Wakamiya, A., Taniguchi, T. and Yamaguchi, S., Angew. Chem. Int. Ed., 2006, 45:3170 doi: 10.1002/(ISSN)1521-3773
31. [31]
  Zhao, R., Dou, C., Xie, Z., Liu, J. and Wang, L., Angew. Chem. Int. Ed., 2016, 55:5313 doi: 10.1002/anie.201601305
32. [32]
  Dou, C., Ding, Z., Zhang, Z., Xie, Z., Liu J. and Wang, L., Angew. Chem. Int. Ed., 2015, 54:3648 doi: 10.1002/anie.201411973
33. [33]
  Dou, C., Long, X., Ding, Z., Xie, Z., Liu, J. and Wang, L., Angew. Chem. Int. Ed., 2016, 55:1436 doi: 10.1002/anie.201508482
34. [34]
  Long, X., Ding, Z., Dou, C., Zhang, J., Liu, J. and Wang, L., Adv. Mater., 2016, 28:6504 doi: 10.1002/adma.201601205
35. [35]
  Ding, Z., Long, X., Dou, C., Liu, J. and Wang, L., Chem. Sci., 2016, 7:6197 doi: 10.1039/C6SC01756H
36. [36]
  Blouin, N., Michaud, A. and Leclerc, M., Adv. Mater., 2007, 19:2295 doi: 10.1002/(ISSN)1521-4095
37. [37]
  Liao, S.H., Jhuo, H.J., Cheng, Y.S. and Chen, S.A., Adv. Mater., 2013, 25:4766 doi: 10.1002/adma.v25.34
38. [38]
  He, Z., Zhong, C., Su, S., Xu, M., Wu, H. and Cao, Y., Nat. Photon., 2012, 6:591
1. [1]
  Xinyu Tian , Jiaxiang Guo , Zeyi Li , Shihou Sheng , Tianyu Zhang , Xianfei Li , Chuandong Dou . Control over electronic structures of organic diradicaloids via precise B/O-heterocycle fusion. Chinese Chemical Letters, 2025, 36(1): 110174-. doi: 10.1016/j.cclet.2024.110174
2. [2]
  Yaohua Li , Qi Cao , Xuanhua Li . Tailoring the configuration of polymer passivators in perovskite solar cells. Chinese Journal of Structural Chemistry, 2025, 44(2): 100413-100413. doi: 10.1016/j.cjsc.2024.100413
3. [3]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
4. [4]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
5. [5]
  Luyan Shi , Ke Zhu , Yuting Yang , Qinrui Liang , Qimin Peng , Shuqing Zhou , Tayirjan Taylor Isimjan , Xiulin Yang . Phytic acid-derivative Co₂B-CoPO_x coralloidal structure with delicate boron vacancy for enhanced hydrogen generation from sodium borohydride. Chinese Chemical Letters, 2024, 35(4): 109222-. doi: 10.1016/j.cclet.2023.109222
6. [6]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
7. [7]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
8. [8]
  Jing REN , Ruikui YAN , Xiaoli CHEN , Huali CUI , Hua YANG , Jijiang WANG . Synthesis and fluorescence sensing of a highly sensitive and multi-response cadmium coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 574-586. doi: 10.11862/CJIC.20240287
9. [9]
  Shuwen SUN , Gaofeng WANG . Design and synthesis of a Zn(Ⅱ)-based coordination polymer as a fluorescent probe for trace monitoring 2, 4, 6-trinitrophenol. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 753-760. doi: 10.11862/CJIC.20240399
10. [10]
  Jinge Zhu , Ailing Tang , Leyi Tang , Peiqing Cong , Chao Li , Qing Guo , Zongtao Wang , Xiaoru Xu , Jiang Wu , Erjun Zhou . Chlorination of benzyl group on the terminal unit of A₂-A₁-D-A₁-A₂ type nonfullerene acceptor for high-voltage organic solar cells. Chinese Chemical Letters, 2025, 36(1): 110233-. doi: 10.1016/j.cclet.2024.110233
11. [11]
  Wenbiao Zhang , Bolong Yang , Zhonghua Xiang . Atomically dispersed Cu-based metal-organic framework directly for alkaline polymer electrolyte fuel cells. Chinese Chemical Letters, 2025, 36(2): 109630-. doi: 10.1016/j.cclet.2024.109630
12. [12]
  Jun Guo , Zhenbang Zhuang , Wanqiang Liu , Gang Huang . "Co-coordination force" assisted rigid-flexible coupling crystalline polymer for high-performance aqueous zinc-organic batteries. Chinese Chemical Letters, 2024, 35(9): 109803-. doi: 10.1016/j.cclet.2024.109803
13. [13]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
14. [14]
  Xiaoman Dang , Zhiying Wu , Tangxin Xiao , Zhouyu Wang , Leyong Wang . Highly robust supramolecular polymer networks crosslinked by metallacycles. Chinese Chemical Letters, 2024, 35(12): 110208-. doi: 10.1016/j.cclet.2024.110208
15. [15]
  Qiang Fu , Shouhong Sun , Kangzhi Lu , Ning Li , Zhanhua Dong . Boron-doped carbon dots: Doping strategies, performance effects, and applications. Chinese Chemical Letters, 2024, 35(7): 109136-. doi: 10.1016/j.cclet.2023.109136
16. [16]
  Qihang Wu , Hui Wen , Wenhai Lin , Tingting Sun , Zhigang Xie . Alkyl chain engineering of boron dipyrromethenes for efficient photodynamic antibacterial treatment. Chinese Chemical Letters, 2024, 35(12): 109692-. doi: 10.1016/j.cclet.2024.109692
17. [17]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
18. [18]
  Huimin Gao , Zhuochen Yu , Xuze Zhang , Xiangkun Yu , Jiyuan Xing , Youliang Zhu , Hu-Jun Qian , Zhong-Yuan Lu . A mini review of the recent progress in coarse-grained simulation of polymer systems. Chinese Journal of Structural Chemistry, 2024, 43(5): 100266-100266. doi: 10.1016/j.cjsc.2024.100266
19. [19]
  Dong Lv , Xuelei Liu , Wei Li , Qiang Zhang , Xinhong Yu , Yanchun Han . Single droplet formation by controlling the viscoelasticity of polymer solutions during inkjet printing. Chinese Chemical Letters, 2024, 35(6): 109401-. doi: 10.1016/j.cclet.2023.109401
20. [20]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(864)
HTML views(33)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142