Citation: Ru-yan Zhao, Chuan-dong Dou, Jun Liu, Li-xiang Wang. An Alternating Polymer of Two Building Blocks Based on B←N Unit: Non-fullerene Acceptor for Organic Photovoltaics[J]. Chinese Journal of Polymer Science, ;2017, 35(2): 198-206. doi: 10.1007/s10118-017-1878-9 shu

An Alternating Polymer of Two Building Blocks Based on B←N Unit: Non-fullerene Acceptor for Organic Photovoltaics

Ru-yan Zhao ^a,b ,
Chuan-dong Dou ^a,, ,
Jun Liu ^a,, ,
Li-xiang Wang ^a

a.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Chuan-dong Dou, chuandong.dou@ciac.ac.cn Jun Liu, liujun@ciac.ac.cn
Received Date: 15 July 2016
Revised Date: 3 August 2016
Accepted Date: 4 August 2016

Fund Project: the National Natural Science Foundation of China 51373165the National Natural Science Foundation of China 21404099financially supported by the 973 Program 2014CB643504the State Key Laboratory of Supramolecular Structure and Materials in Jilin University sklssm201608the National Natural Science Foundation of China 21574129the “Thousand Talents Program” of China, the Strategic Priority Research Program of the Chinese Academy of Sciences XDB12010200

B←N coordination bond can be used to develop polymer electron acceptors for efficient all-polymer solar cells (all-PSCs). Here, we report a new alternating conjugated polymer containing two building blocks based on B←N unit. The polymer exhibits strong light absorption in the visible range, low-lying LUMO/HOMO energy levels and moderate electron mobility. The resulting all-PSC devices exhibit power conversion efficiencies of 1.50%-2.47%.
- All-polymer solar cells,
- Polymer acceptor,
- Boron,
- B←N coordination bond
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