Citation: Fan Liu, Li-li Mei, Zhi-lin Tan, Guo-ping Yan, Jun-fang Guo, Qiao Zhang, Hui Liu, Jun Yang. Studies on Microwave-assisted Ring-opening Polymerization and Property of Poly(9-phenyl-2,4,8,10-tetraoxaspiro-[5,5]undcane-3-one)[J]. Chinese Journal of Polymer Science, ;2016, 34(11): 1330-1338. doi: 10.1007/s10118-016-1852-y shu

Studies on Microwave-assisted Ring-opening Polymerization and Property of Poly(9-phenyl-2,4,8,10-tetraoxaspiro-[5,5]undcane-3-one)

School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan 430074, China

Corresponding author: Guo-ping Yan, guopyan2006@163.com
Received Date: 12 June 2016
Revised Date: 15 July 2016
Accepted Date: 11 August 2016

Fund Project: Wuhan Scientific and Technological Project 2013010501010131the National Natural Science Foundation of China 51373128"E+" double-major program, and Innovation Fund for post-graduate education CX2014058Wuhan Science and Technology Innovation Team of Hi-tech Industrial Project, Hubei Province 2015070504020217University Students' President Funded Project, Wuhan Institute of Technology 2015004Key National Research and Development Program 2016YFB1101302

Poly(9-phenyl-2,4,8,10-tetraoxaspiro-[5,5]undcane-3-one) (PPTC) was synthesized by the microwave-assisted ring-opening polymerization (MROP) of a six-membered cyclic carbonate monomer 9-phenyl-2,4,8,10-tetraoxaspiro-[5,5]undcane-3-one (PTC) with tin(Ⅱ) 2-ethylhexanoate (Sn(Oct)₂) or aluminum isopropoxide (Al(OⁱPr)₃) as the catalysts. The obtained polycarbonates were further reduced by apalladium/carbonate catalyst (10% Pd/C) to afford partly deprotected polycarbonates containing hydroxyl groups (HPPTC). These two types of polycarbonates were characterized by ¹H-NMR, Fourier transform infrared spectroscopy (FTIR), UV, gel permeation chromatography (GPC), differential scanning calorimetry (DSC), and automatic contact-angle measurements. The influence of the feed molar ratio of monomer-to-catalyst, the microwave irradiation power and the reaction time on the polymerization was also studied. The experimental results showed that HPPTC possessed significantly higher hydrophilicity and water absorption rate than PPTC.
- Biodegradable polycarbonate,
- Microwave-assisted polymerization,
- Ring-opening polymerization,
- Hydrophilicity
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