Citation: Zhang Li-qin, Chen Li-wen, Zhong Ming, Shi Fu-kuan, Liu Xiao-ying, Xie Xu-ming. Phase Transition Temperature Controllable Poly(acrylamide-co-acrylic acid) Nanocomposite Physical Hydrogels with High Strength[J]. Chinese Journal of Polymer Science, ;2016, 34(10): 1261-1269. doi: 10.1007/s10118-016-1848-7 shu

Phase Transition Temperature Controllable Poly(acrylamide-co-acrylic acid) Nanocomposite Physical Hydrogels with High Strength

Laboratory of Advanced Materials (MOE), Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: Xie Xu-ming, xxm-dce@mail.tsinghua.edu.cn
Received Date: 11 April 2016
Revised Date: 21 May 2016
Accepted Date: 28 May 2016

Fund Project: State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University LK1404the National Nature Science Foundation of China 21474058Tsinghua University Scientific Research Project 2014Z22069

Poly(acrylamide-co-acrylic acid) nanocomposite physical (P(AAm-co-AAc)NCP) hydrogels have been prepared through the in situ free radical solution polymerization based on a “single network, dual cross-linkings” strategy. The P(AAm-co-AAc) NCP hydrogels are composed of nanobrushes of P(AAm-co-AAc) chains grafted on the surface of vinyl-hybrid silica nanoparticles (VSNPs). In the hydrogel system, the VSNPs act as the “analogous chemical cross-linking points” once the hydrogen bonds formed between the P(AAm-co-AAc) chains of the nanobrushes, thus leading to the fabrication of high-strength P(AAm-co-AAc) NCP hydrogels. Compared with conventional thermosensitive P(AAm-co-AAc) hydrogels, the P(AAm-co-AAc) NCP hydrogels have a broader range of phase transition temperature, which can be adjusted by altering the monomer ratio, the VSNPs concentration, the addition of urea and N, N-dimethylacrylamide (DMAAm). At the same time, the mechanical properties of the P(AAm-co-AAc) NCP hydrogels have been improved significantly by the introduction of VSNPs. Furthermore, both the phase transition and the tensile strength of the P(AAm-co-AAc) NCP hydrogels are largely influenced when Fe³⁺ ions are introduced as the ionic crosslinkers into the hydrogel networks.
- Poly(acrylamide-co-acrylic acid),
- Nanocomposite physical hydrogels,
- Phase transition,
- High strength
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