Citation: Hong-shuang Guo, Mei-fang Liu, Yi Han, Sheng Han, Yu-lan Chen. Synthesis and Characterization of S,N-Heteroacenes by Bischler-Napieralski Reaction[J]. Chinese Journal of Polymer Science, ;2016, 34(11): 1319-1329. doi: 10.1007/s10118-016-1846-9 shu

Synthesis and Characterization of S,N-Heteroacenes by Bischler-Napieralski Reaction

Hong-shuang Guo ^a,b ,
Mei-fang Liu ^c ,
Yi Han ^b ,
Sheng Han ^a,, ,
Yu-lan Chen ^b,,

a.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China
b.
Tianjin Key Laboratory of Molecular Optoelectronic Science, Tianjin University, Tianjin 300072, China
c.
Department of Chemistry, Weifang University, Weifang 261061, China

Corresponding author: Sheng Han, hansheng654321@sina.com Yu-lan Chen, chenyl@iccas.ac.cn
Received Date: 16 May 2016
Revised Date: 22 May 2016
Accepted Date: 25 May 2016

Fund Project: the Open Project of the State Key Laboratory of Supramolecular Structure and Materials SKLSSM201505the National Natural Science Foundation of China 51503142Shanghai Municipal Education Commission Boosting Project 15cxy39Shanghai Leading Academic Discipline Project J51503

Bischler-Napieralski cyclization has been successfully employed to prepare planar S,N-heteroacenes (SNHs) with the analogue structures to 1,10-phenanthroline. The opto-/electrical properties and the packing modes of these S,Nheteroacenes were examined, which were dependent on the structure of the fused groups. SNH-based copolymers with high molecular weight and good solubility in common organic solvents or water have been synthesized by Suzuki-Miyaura-Schlüter polycondensation. The photophysical property studies revealed that the copolymers may be a promising chemosensor material.
- Bischler-Napieralski cyclization,
- Suzuki-Miyaura-Schlüter,
- polycondensation,
- S,N-heteroacenes,
- Stimuliresponsive
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