Citation: Chen-yi Wang, Wen-tao Chen, Chang Xu, Xiao-yan Zhao, Jian Li. Fluorinated Polyimide/POSS Hybrid Polymers with High Solubility and Low Dielectric Constant[J]. Chinese Journal of Polymer Science, ;2016, 34(11): 1363-1372. doi: 10.1007/s10118-016-1845-x shu

Fluorinated Polyimide/POSS Hybrid Polymers with High Solubility and Low Dielectric Constant

Chen-yi Wang ^a,b,, ,
Wen-tao Chen ^a ,
Chang Xu ^a ,
Xiao-yan Zhao ^a,, ,
Jian Li ^a

a.
School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China
b.
State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an 710049, China

Corresponding author: Chen-yi Wang, wangcy@cczu.edu.cn Xiao-yan Zhao, zhaoxiaoyan@cczu.edu.cn
Received Date: 22 May 2016
Revised Date: 9 June 2016
Accepted Date: 13 June 2016

Fund Project: Natural Science Foundation of Jiangsu Province BK20141173Opening Project of State Key Laboratory of Electrical Insulation and Power Equipment EIPE14206the National Natural Science Foundation of China 21404016

A series of fluorinated polyimide/POSS hybrid polymers (FPI-4-FPI-16) were prepared via a facile synthetic route using 2,2'-bis(trifluoromethyl)benzidine, 4,4'-oxydiphthalic dianhydride and monofunctional POSS as starting materials. The hybrid polymers showed excellent solubility and film formation ability. Flexible and robust hybrid films could be conveniently obtained via solution-casting. The hybrid films demonstrated low dielectric constants and high thermal stability. Their dielectric constants were in the range of 2.47-2.92 at 1 MHz measured for their capacitance, and were tunable and decreased with an increase of POSS content. Their 10% weight loss temperatures were in the range of 539-591℃ and the weight residual at 800℃ ranged from 48% to 53% in nitrogen atmosphere. These hybrid films also possessed good mechanical properties and hydrophobic characteristics. This work could provide a potential strategy for the preparation of fluorinated polyimide/POSS hybrid polymers.
- Polyimide,
- Hybrid polymers,
- Solubility,
- Dielectric properties
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