Citation: Noor Rehman, Maria Inez G. de Miranda, Simone M. L. Rosa, Clara I. D. Bica. Reinforcement of Hydroxypropylcellulose Films by Cellulose Nanocrystals in the Presence of Surfactants[J]. Chinese Journal of Polymer Science, ;2016, 34(11): 1301-1310. doi: 10.1007/s10118-016-1844-y shu

Reinforcement of Hydroxypropylcellulose Films by Cellulose Nanocrystals in the Presence of Surfactants

a.
Instituto de Química, Universidade Federal do Rio Grande do Sul, 91501-970, Porto Alegre/RS, Brazil
b.
Department of Chemistry, Shaheed Benazir Bhutto University, 18000, Sheringal Dir(Upper) KPK, Pakistan
c.
Instituto de Ciências Exatas e Tecnológicas, Universidade FEEVALE, Campus Ⅱ, 93525-075, Novo Hamburgo/RS, Brazil

Corresponding author: Noor Rehman, noor_rehman33@yahoo.com Clara I. D. Bica, claraism@iq.ufrgs.br
Received Date: 18 April 2016
Revised Date: 25 May 2016
Accepted Date: 6 June 2016

Hydroxypropylcellulose (HPC) films were prepared by casting with cellulose nanocrystals in the presence of anionic surfactant sodium dodecylsulphate (SDS) and cationic surfactant hexadecyltrimethyl ammonium bromide (CTAB). The cellulose nanocrystals were isolated from maize straw, a biomass source produced in huge quantities as an agrowaste in Brazil. These bionanocomposite films had good transparency and their surface hydrophilic character was evidenced by static contact angle measurements. Thermogravimetry (TGA) measurement revealed that nanocrystals and surfactants changed the thermal stability of the HPC films. Dynamic mechanical analysis (DMA) showed that the tensile storage and loss moduli of the HPC films increased by increasing the contents of cellulose nanocrystals and surfactants, especially in the case of CTAB. This good reinforcing effect of HPC matrix can be explained as due to electrostatic attractive interactions brought about by the presence of CTAB and the nanocrystals.
- Hydroxypropylcellulose,
- Cellulose nanocrystals,
- Bionanocomposites,
- Maize straw,
- Micellization
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沈阳化工大学材料科学与工程学院沈阳 110142