Citation: Min-fang An, Hao-jun Xu, You Lv, Li Zhang, Qun Gu, Feng Tian, Zong-bao Wang. The Influence of Chitin Nanocrystals on Structural Evolution of Ultra-high Molecular Weight Polyethylene/Chitin Nanocrystal Fibers in Hot-drawing Process[J]. Chinese Journal of Polymer Science, ;2016, 34(11): 1373-1385. doi: 10.1007/s10118-016-1843-z shu

The Influence of Chitin Nanocrystals on Structural Evolution of Ultra-high Molecular Weight Polyethylene/Chitin Nanocrystal Fibers in Hot-drawing Process

Min-fang An ^a ,
Hao-jun Xu ^a ,
You Lv ^a ,
Li Zhang ^a ,
Qun Gu ^b ,
Feng Tian ^c ,
Zong-bao Wang ^a,,

a.
Ningbo Key Laboratory of Specialty Polymers, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
b.
College of Material Engineering, Ningbo University of Technology, Ningbo 3151006, China
c.
Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204, China

Corresponding author: Zong-bao Wang, wangzongbao@nbu.edu.cn
Received Date: 27 March 2016
Revised Date: 21 June 2016
Accepted Date: 18 July 2016

Fund Project: the National Natural Science Foundation of China 51273210

Ultra-high molecular weight polyethylene (UHMWPE)/chitin nanocrystal (CNC) fibers were prepared. Compared with the pure UHMWPE fibers, the ultimate tensile strength and Young's modulus of UHMWPE/CNC fibers are improved by 15.7% and 49.6%, respectively, with the addition of chitin nanocrystals (CNCs) of 1 wt%. The melting temperature (T_m) of UHMWPE/CNC fibers was higher than that of pure UHMWPE fibers. Pure UHMWPE fibers and UHMWPE/CNC fibers were characterized with respect to crystallinity, orientation and kebab structure by wide-angle X-ray diffraction (WAXD), small-angle X-ray scattering (SAXS) and scanning electron microscopy (SEM). It is found that the CNCs act as the shish structure in UHMWPE/CNC fibers and the kebab crystals are grown around the CNCs. There was almost no difference between pure UHMWPE fibers and UHMWPE/CNC fibers in orientation. But the degree of crystallinity of various stages of UHMWPE/CNC fibers was respectively higher than the corresponding stage of pure UHMWPE fibers. Moreover, the addition of 1 wt% CNCs improved the thickness of kebab crystals and accelerated the transformation of kebab to shish.
- UHMWPE fibers,
- Chitin nanocrystals,
- Shish-kebab,
- Orientation
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