Citation: Xu Ding-feng, Cai Jie, Zhang Li-na. High Strength Cellulose Composite Films Reinforced with Clay for Applications as Antibacterial Materials[J]. Chinese Journal of Polymer Science, ;2016, 34(10): 1281-1289. doi: 10.1007/s10118-016-1840-2 shu

High Strength Cellulose Composite Films Reinforced with Clay for Applications as Antibacterial Materials

College of Chemistry & Molecule Sciences, Wuhan University, Wuhan 430072, China

Corresponding author: Cai Jie, caijie@whu.edu.cn Zhang Li-na, zhangln@whu.edu.cn
Received Date: 11 April 2016
Revised Date: 18 June 2016
Accepted Date: 6 July 2016

Fund Project: the Major Program of National Natural Science Foundation of China 21334005the National Natural Science Foundation of China 20874079

High strength cellulose composite films with antibacterial activities were prepared by dispersing montmorillonites (MMT) into cellulose solution in LiOH/urea aqueous solvent followed by regeneration in ethanol coagulation bath, and then by soaking in 5 wt% hexadecylpyridine bromide ethanol solutions to induce the antibacterial action. The cellulose/MMT composite films were characterized by field emission scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, FTIR, UV-spectra, wide angle X-ray diffraction and mechanical test. The results revealed that MMT was dispersed well in the cellulose matrix to form layer structure with a thickness of approximately 3 nm. The mechanical properties of the cellulose/MMT composite films were significantly improved to achieve 132 MP for tensile strength as a result of the MMT delamination. The hexadecylpyridine bromide was fixed well in the cellulose/MMT matrix through cation exchange, leading to the excellent antibacterial activities against Staphylococcus aureus and Escherichia coli, which is important in their practical applications.
- Cellulose/MMT composite films,
- Antibacterial activities,
- High strength,
- Hexadecylpyridine bromide
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