Citation: Li Yue, Li Su-qing, Zhao Jing-bo, Zhang Zhi-yuan, Zhang Jun-ying, Yang Wan-tai. Synthesis and Characterization of Crystallizable Aliphatic Thermoplastic Poly(ester urethane) Elastomers through a Non-isocyanate Route[J]. Chinese Journal of Polymer Science, ;2016, 34(10): 1220-1233. doi: 10.1007/s10118-016-1839-8 shu

Synthesis and Characterization of Crystallizable Aliphatic Thermoplastic Poly(ester urethane) Elastomers through a Non-isocyanate Route

Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Zhao Jing-bo, zhaojb@mail.buct.edu.cn
Received Date: 18 March 2016
Revised Date: 7 June 2016
Accepted Date: 9 June 2016

Fund Project: the National Natural Science Foundation of China 21244006 and 50873013

A simple non-isocyanate route is developed for synthesizing crystallizable aliphatic thermoplastic poly(ester urethane) elastomers (TPEURs) with good thermal and mechanical properties. Three prepolymers of 1,6-bis(hydroxyethyloxycarbonylamino) hexane (BHCH), i.e. PrePBHCHs, were prepared through the self-transurethane polycondensation of BHCH. A poly(butylene adipate) prepolymer (PrePBA) with terminal HO― groups was prepared and used as a polyester glycol. A series of TPEURs were prepared by the co-polycondensation of the PrePBHCHs with PrePBA at 170 ℃ under a reduced pressure of 399 Pa. The TPEURs were characterized by gel permeation chromatography, FTIR, ¹H-NMR, differential scanning calorimetry, thermogravimetric analysis, wide-angle X-ray diffraction, atomic force microscopy, and tensile test. The TPEURs exhibited M_n up to 23300 g/mol, M_w up to 51100 g/mol, T_g ranging from -33.8 ℃ to -3.1 ℃, T_m from 94.3 ℃ to 111.9 ℃, initial decomposition temperature over 274.7 ℃, tensile strength up to18.8 MPa with a strain at break of 450.0%, and resilience up to 77.5%. TPU elastomers with good crystallization and mechanical properties were obtained through a non-isocyanate route.
- Non-isocyanate route,
- Thermoplastic polyurethane elastomers,
- Diurethanediol,
- Transurethane polycondensation,
- Poly(ester urethane)s
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