Citation: Ma Hai-li, Chen Hao, Hou Sheng-zhen, Tan Ye-bang. Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain[J]. Chinese Journal of Polymer Science, ;2016, 34(10): 1251-1260. doi: 10.1007/s10118-016-1837-x shu

Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain

School of Chemistry and Engineering, Shandong University, Jinan 250100, China

Corresponding author: Tan Ye-bang, ybtan@sdu.edu.cn
Received Date: 11 April 2016
Revised Date: 14 May 2016
Accepted Date: 19 May 2016

Fund Project: the National Natural Science Foundation of China 21374055

Thermo-gelation polymers have attracted increasing attention over decades. However, rare facile tuning method of sol-gel transition temperature restricted the wider application. Preceding study indicated that supramolecular interactions demonstrated a powerful means to control the structure and property of polymeric materials. Here we designed an N-isopropylacrylamide (NIPAM) based thermo-sensitive copolymer with naphthyl (Np) on its side chain. Positive-charged side-chain ternary complex was formed with cucurbit[8]uril (CB[8]) and methylviologen (MV²⁺) via CB[8]-enhanced intermolecular charge-transfer (CT) interaction. Introducing the ternary complex CB[8]/MV²⁺/Np on side-chain altered microstructure of macromolecular chains and led to a strong tendency for thermo gelation. Altering content of CB[8] and MV²⁺ changed content of the positive-charged side-chain ternary complex and varied gelation temperature. Therefore, introducing supramolecular interaction endowed the hydrogel with tunable gelation property.
- Thermo-sensitive copolymer,
- Supramolecular chemistry,
- Cucurbit[8]uril,
- Charge transfer interaction,
- Gelation
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