Citation: Shen Jie, Xu Jing, Hu Yang, Sun Jian-wu, Li Ling-xiao, Kan Cheng-you. Investigation of Cationic Soapless P(St-co-DMAEMA) Latex and Its Electrostatic Adsorption of Laponite[J]. Chinese Journal of Polymer Science, ;2016, 34(10): 1240-1250. doi: 10.1007/s10118-016-1829-x shu

Investigation of Cationic Soapless P(St-co-DMAEMA) Latex and Its Electrostatic Adsorption of Laponite

Department of Chemical Engineering, Key Laboratory of Advanced Materials of Ministry of Education, Tsinghua University, Beijing 100084, China

Corresponding author: Kan Cheng-you, kancy@mail.tsinghua.edu.cn
Received Date: 6 April 2016
Revised Date: 29 April 2016
Accepted Date: 1 May 2016

Fund Project: the National Basic Research Program of China 2014CB932202

Cationic poly(styrene-co-N, N-dimethylaminoethyl methacrylate) (P(St-co-DMAEMA)) latexes were prepared in the absence of surfactant by using 2, 2'-azobis (2-methylpropionamidine) dihydrochloride (AIBA) as the initiator. The effects of the AIBA concentration, HCl/DMAEMA molar ratio and DMAEMA amount on the emulsion polymerization and the latex properties were investigated. The particle morphology and size, the zeta potential and the amino distribution of the P(St-co-DMAEMA) latexes were characterized by transmission electron microscope (TEM), dynamic light scattering (DLS) and conductometric titration, respectively. Results showed that the emulsion polymerization performed smoothly with high monomer conversion and narrow particle size distribution under the optimized conditions with AIBA concentration of 1 wt%, HCl/DMAEMA molar ratio of 1.2 and DMAEMA content of 5 wt%. The diameter of the dried latex particles decreased and the density of amino groups on the particle surfaces increased with increasing the DMAEMA content. The zeta potential of the P(St-co-DMAEMA) latexes was pH-dependent and the zero point was around at pH 7.2. A facile method was developed to fabricate P(St-co-DMAEMA)/laponite hybrid nanoparticles via electrostatic adsorption, in which the loading capacity of laponite platelets reached 17.7 wt%, and the resultant hybrid nanoparticles showed good thermal stability.
- Cationic latex,
- Soapless emulsion polymerization,
- DMAEMA,
- Polymeric-laponite nanoparticles
1. [1]
  Chiu, W.Y. and Shih, C.C., J. Appl. Polym. Sci., 1986, 31 (7): 2117 doi: 10.1002/app.1986.070310715
2. [2]
  Aramendia, E., Mallegol, J., Jeynes, C., Barandiaran, M. J., Keddie, J.L. and Asua, J.M., Langmuir, 2003, 19: 3212 doi: 10.1021/la0267950
3. [3]
  Yamamoto, T., Nakayama, M., Kanda, Y. and Higashitani, K., J. Colloid Interf. Sci., 2006, 297(1): 112 doi: 10.1016/j.jcis.2005.10.025
4. [4]
  Shibuya, K., Nagao, D., Ishii, H. and Konna, M., Polymer, 2014, 55(2): 535 doi: 10.1016/j.polymer.2013.12.039
5. [5]
  Lu, Y.S., Xia, Y. and Larock, R.C., Prog. Org. Coat., 2011, 71(4): 336 doi: 10.1016/j.porgcoat.2011.03.027
6. [6]
  Wang, J.S., Hu, Y., Shen, J., Huang, X.Y. and Kan, C.Y., Chinese J. Polym. Sci., 2014, 32(5): 519 doi: 10.1007/s10118-014-1438-5
7. [7]
  Basinska, T. and Slomkowski, S., Chem. Pap., 2012, 66(5): 352
8. [8]
  Kang, K., Kan, C.Y., Du, Y. and Liu, D.S., J. Appl. Polym. Sci., 2004, 92(1): 433 doi: 10.1002/(ISSN)1097-4628
9. [9]
  Deng, W., Li, R.L., Zhang, M.J., Gong, L.X. and Kan, C.Y., J. Colloid Interf. Sci., 2010, 349(1): 122 doi: 10.1016/j.jcis.2010.05.033
10. [10]
  Ni, H.M., Du, Y.Z., Ma, G.H., Nagai, M. and Omi, S., Macromolecules, 2001, 34(19): 6577 doi: 10.1021/ma010829d
11. [11]
  Zou, D., Li, X.F., Zhu, X.L. and Kong, X.Z., Chinese J. Polym. Sci., 2012, 30(2): 278 doi: 10.1007/s10118-012-1113-7
12. [12]
  Karabacak, R.B., Erdem, M., Yurdakal, S., Cimen, Y. and Turk, H., Mater. Chem. Phys., 2014, 144(3): 498 doi: 10.1016/j.matchemphys.2014.01.026
13. [13]
  Bazin, G. and Zhu, X.X., Soft Matter, 2010, 6(17): 4189 doi: 10.1039/c0sm00127a
14. [14]
  Talingting, M.R., Ma, Y.H., Simmons, C. and Webber, S.E., Langmuir, 2000, 16(2): 862 doi: 10.1021/la9901027
15. [15]
  Ramos, J., Forcada, J. and Hidalgo-Alvarez, R., Chem. Rev., 2014, 114(1): 367 doi: 10.1021/cr3002643
16. [16]
  Li, X.L., Liu, G.Q., Yan, W., Chu, P.K., Yeung, K.W.K., Wu, S.L., Yi, C.F. and Xu, Z.S., J. Magn. Magn. Mater., 2012, 324(7): 1410 doi: 10.1016/j.jmmm.2011.11.056
17. [17]
  Okubo, M., Ito, A., Mori, H. and Suzuki, T., Colloid Polym. Sci., 2003, 281(2): 168 doi: 10.1007/s00396-002-0767-z
18. [18]
  Hu, Y., Wang, J.S., Zhang, H., Jiang, G.Q. and Kan, C.Y., Mat. Sci. Eng. C, 2014, 45: 1 doi: 10.1016/j.msec.2014.08.061
19. [19]
  Cheng, X.J., Zhao, Q. and Yang, Y.K., J. Mater. Sci., 2010, 45(3): 777 doi: 10.1007/s10853-009-4000-z
20. [20]
  Karabacak, R.B. and Turk, H., J. Macromol. Sci. A, 2012, 49(8): 680 doi: 10.1080/10601325.2012.697045
21. [21]
  Chaudhuri, R.G. and Paria, S., Chem. Rev., 2012, 112(4): 2373 doi: 10.1021/cr100449n
22. [22]
  Taniguchi, T., Kashiwakura, T., Inada, T., Kunisada, Y., Kasuya, M., Kohri, M. and Nakahira, T., J. Colloid Interf. Sci., 2010, 347(1): 62 doi: 10.1016/j.jcis.2010.03.019
23. [23]
  Liu, Y.D., Quan, X.M., Bora, H., Yong, K.K. and Hyoung, J.C., Langmuir, 2014, 30(7): 1729 doi: 10.1021/la4050072
24. [24]
  Imhof, A., Langmuir, 2001, 17(12): 3579 doi: 10.1021/la001604j
25. [25]
  Hu, Y., Wang, J.S., Cheng, G.Z., Shen, J. and Kan, C.Y., Chinese J. Chem., 2014, 32(7): 579 doi: 10.1002/cjoc.201400098
26. [26]
  Cauvin, S., Colver, P.J. and Bon, S.A.F., Macromolecules, 2005, 38(19): 7887 doi: 10.1021/ma051070z
27. [27]
  Caruso, R.A., Susha, A. and Caruso, F., Chem. Mater., 2001, 13(2): 400 doi: 10.1021/cm001175a
28. [28]
  Wang, Y.J., Angelatos, A.S. and Caruso, F., Chem. Mater., 2008, 20(3): 848 doi: 10.1021/cm7024813
29. [29]
  Dziomkina, N.V., Hempenius, M.A. and Vancso, G.J., Eur. Polym. J., 2006, 42(1): 81 doi: 10.1016/j.eurpolymj.2005.07.015
30. [30]
  Yamamoto, T. and Kawaguchi, K., Colloid Polym. Sci., 2015, 293(3): 1003 doi: 10.1007/s00396-015-3511-1
31. [31]
  Kim, T.H., Lee, K.H. and Kwon, Y.K., J. Colloid Interf. Sci., 2006, 304: 370 doi: 10.1016/j.jcis.2006.08.059
32. [32]
  van de Wetering, P., Moret, E.E., Schuurmans-Nieuwenbroek, N.M.E., van Steenbergen, M.J. and Hennink, W.E., Bioconjugate Chem., 1999, 10(4): 589 doi: 10.1021/bc980148w
33. [33]
  Jiang, Y.M., Li, B.T., Wang, W.J., Xu, M. and Kan, C.Y., Chinese J. Polym. Sci., 2014, 32(2): 177 doi: 10.1007/s10118-014-1387-z
34. [34]
  Bourgeat-Lami, E. and Lansalot, M., Adv. Polym. Sci., 2010, 233: 53 doi: 10.1007/978-3-642-16060-8
35. [35]
  Chen, M., Zhou, S.X., You, B. and Wu, L.M., Macromolecules, 2005, 38(15): 6411 doi: 10.1021/ma050132i
36. [36]
  Zhou, J., Chen, M., Qiao, X.G. and Wu, L.M., Langmuir, 2006, 22(24): 10175 doi: 10.1021/la062220h
37. [37]
  Cheng, G.Z., Huang, X.Y., Zhang, H., Hu, Y. and Kan, C.Y., RSC Adv., 2014, 4(55): 29042 doi: 10.1039/C4RA01360C
38. [38]
  Chen, M., Zhou, J., Xie, L., Gu, G.X. and Wu, L.M., J. Phys. Chem. C, 2007, 111(32): 11829 doi: 10.1021/jp0711085
39. [39]
  Pojanavaraphan, T., Chirasakulkarun, A., Muksing, N. and Magaraphan, R., J. Appl. Polym. Sci., 2009, 112(3): 1552 doi: 10.1002/app.v112:3
1. [1]
  Yiran Tao , Chunlei Dai , Zhaoxiang Xie , Xinru You , Kaiwen Li , Jun Wu , Hai Huang . Redox responsive polymeric nanoparticles enhance the efficacy of cyclin dependent kinase 7 inhibitor for enhanced treatment of prostate cancer. Chinese Chemical Letters, 2024, 35(8): 109170-. doi: 10.1016/j.cclet.2023.109170
2. [2]
  Tingting Hu , Chao Shen , Xueyan Wang , Fengbo Wu , Zhiyao He . Tumor microenvironment-sensitive polymeric nanoparticles for synergetic chemo-photo therapy. Chinese Chemical Letters, 2024, 35(11): 109562-. doi: 10.1016/j.cclet.2024.109562
3. [3]
  Shuang Liang , Jianjun Yao , Dan Liu , Mengli Zhou , Yong Cui , Zhaohui Wang . Tumor-responsive covalent organic polymeric nanoparticles enhancing STING activation for cancer immunotherapy. Chinese Chemical Letters, 2025, 36(3): 109856-. doi: 10.1016/j.cclet.2024.109856
4. [4]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406
5. [5]
  Rongjian Chen , Jiahui Liu , Caixia Lin , Yuanming Li , Yanhou Geng , Yaofeng Yuan . Synthesis and properties of tetraphenylethene cationic cyclophanes based on o-carborane skeleton. Chinese Chemical Letters, 2024, 35(12): 110074-. doi: 10.1016/j.cclet.2024.110074
6. [6]
  Zhengzhong Zhu , Shaojun Hu , Zhi Liu , Lipeng Zhou , Chongbin Tian , Qingfu Sun . A cationic radical lanthanide organic tetrahedron with remarkable coordination enhanced radical stability. Chinese Chemical Letters, 2025, 36(2): 109641-. doi: 10.1016/j.cclet.2024.109641
7. [7]
  Chong Liu , Ling Li , Jiahui Gao , Yanwei Li , Nazhen Zhang , Jing Zang , Cong Liu , Zhaopei Guo , Yanhui Li , Huayu Tian . The study of antibacterial activity of cationic poly(β-amino ester) regulating by amphiphilic balance. Chinese Chemical Letters, 2025, 36(2): 110118-. doi: 10.1016/j.cclet.2024.110118
8. [8]
  Yingying Yan , Wanhe Jia , Rui Cai , Chun Liu . An AIPE-active fluorinated cationic Pt(Ⅱ) complex for efficient detection of picric acid in aqueous media. Chinese Chemical Letters, 2024, 35(5): 108819-. doi: 10.1016/j.cclet.2023.108819
9. [9]
  Na Wang , Wang Luo , Huaiyi Shen , Huakai Li , Zejiang Xu , Zhiyuan Yue , Chao Shi , Hengyun Ye , Leping Miao . Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system. Chinese Chemical Letters, 2024, 35(5): 108696-. doi: 10.1016/j.cclet.2023.108696
10. [10]
  Ziqin Li , Kai Hao , Longwei Xiang , Huayu Tian . Cationic covalent organic framework nanocarriers integrating both efficient gene silencing and real-time gene detection. Chinese Chemical Letters, 2025, 36(4): 109943-. doi: 10.1016/j.cclet.2024.109943
11. [11]
  Hailong He , Wenbing Wang , Wenmin Pang , Chen Zou , Dan Peng . Double stimulus-responsive palladium catalysts for ethylene polymerization and copolymerization. Chinese Chemical Letters, 2024, 35(7): 109534-. doi: 10.1016/j.cclet.2024.109534
12. [12]
  Yujuan Zhao , Zaiwang Zhao . Monolayer mesoporous nanosheets with surface asymmetry via a dual-emulsion-directed monomicelle assembly. Chinese Journal of Structural Chemistry, 2024, 43(2): 100238-100238. doi: 10.1016/j.cjsc.2024.100238
13. [13]
  Yan Zou , Yin-Shuang Hu , Deng-Hui Tian , Hong Wu , Xiaoshu Lv , Guangming Jiang , Yu-Xi Huang . Tuning the membrane rejection behavior by surface wettability engineering for an effective water-in-oil emulsion separation. Chinese Chemical Letters, 2024, 35(6): 109090-. doi: 10.1016/j.cclet.2023.109090
14. [14]
  Luyu Zhang , Zirong Dong , Shuai Yu , Guangyue Li , Weiwen Kong , Wenjuan Liu , Haisheng He , Yi Lu , Wei Wu , Jianping Qi . Ionic liquid-based in situ dynamically self-assembled cationic lipid nanocomplexes (CLNs) for enhanced intranasal siRNA delivery. Chinese Chemical Letters, 2024, 35(7): 109101-. doi: 10.1016/j.cclet.2023.109101
15. [15]
  Zhenyu Hu , Zhenchun Yang , Shiqi Zeng , Kun Wang , Lina Li , Chun Hu , Yubao Zhao . Cationic surface polarization centers on ionic carbon nitride for efficient solar-driven H₂O₂ production and pollutant abatement. Chinese Chemical Letters, 2024, 35(10): 109526-. doi: 10.1016/j.cclet.2024.109526
16. [16]
  Bing Niu , Honggao Huang , Liwei Luo , Li Zhang , Jianbo Tan . Coating colloidal particles with a well-defined polymer layer by surface-initiated photoinduced polymerization-induced self-assembly and the subsequent seeded polymerization. Chinese Chemical Letters, 2025, 36(2): 110431-. doi: 10.1016/j.cclet.2024.110431
17. [17]
  Xue Zhao , Mengshan Chen , Dan Wang , Haoran Zhang , Guangzhi Hu , Yingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327
18. [18]
  Jian Song , Shenghui Wang , Qiuge Liu , Xiao Wang , Shuo Yuan , Hongmin Liu , Saiyang Zhang . N-Benzyl arylamide derivatives as novel and potent tubulin polymerization inhibitors against gastric cancers: Design, structure–activity relationships and biological evaluations. Chinese Chemical Letters, 2025, 36(2): 109678-. doi: 10.1016/j.cclet.2024.109678
19. [19]
  Yue Pan , Wenping Si , Yahao Li , Haotian Tan , Ji Liang , Feng Hou . Promoting exciton dissociation by metal ion modification in polymeric carbon nitride for photocatalysis. Chinese Chemical Letters, 2024, 35(12): 109877-. doi: 10.1016/j.cclet.2024.109877
20. [20]
  Fei Yin , Erli Yang , Xue Ge , Qian Sun , Fan Mo , Guoqiu Wu , Yanfei Shen . Coupling WO₃₋_x dots-encapsulated metal-organic frameworks and template-free branched polymerization for dual signal-amplified electrochemiluminescence biosensing. Chinese Chemical Letters, 2024, 35(4): 108753-. doi: 10.1016/j.cclet.2023.108753

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(816)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142