Citation: Jian-hua Li, Shuang-shuang Wang, De-bin Zhang, Xing-xing Ni, Qi-qing Zhang. Amino Acids Functionalized Graphene Oxide for Enhanced Hydrophilicity and Antifouling Property of Poly(vinylidene fluoride) Membranes[J]. Chinese Journal of Polymer Science, ;2016, 34(7): 805-819. doi: 10.1007/s10118-016-1808-2 shu

Amino Acids Functionalized Graphene Oxide for Enhanced Hydrophilicity and Antifouling Property of Poly(vinylidene fluoride) Membranes

Institute of Biomedical and Pharmaceutical Technology, Fuzhou University, Fuzhou 350001, China

Corresponding author: Jian-hua Li, jhli_2005@163.com Qi-qing Zhang, zhangqiq@126.com
Received Date: 16 December 2015
Revised Date: 9 March 2016
Accepted Date: 18 March 2016

Herein, functionalized graphene oxide (GO) was prepared by the covalent functionalization with amino acids (lysine, glycine, glutamic acid and tyrosine) in this study. Zeta potential results demonstrated that covalent functionalization of GO with amino acids was favourable for their homogeneous dispersion in water and organic solvents. Based on the higher absolute value of zeta potential and the better dipersion stability of GO-lysine, the PVDF/GO-lysine hybrid membranes were then prepared via the phase inversion induced by immersion precipitation technique. SEM images showed a better pore diameter and porosity distribution on the PVDF/GO-lysine membrane surface. The zeta potential absolute value of the PVDF/GO-lysine membrane surface was higher than that of the virgin PVDF membrane. Furthermore, the PVDF/GO-lysine membranes surface exhibited good hydrophilicity. The water flux of PVDF/GO-lysine membranes can reach two times of that of the virgin PVDF membrane. And the BSA adsorbed amount on PVDF/GO-lysine surface was decreased to 0.82 mg/cm² for PVDF/GO-lysine-8% membrane. Filtration experiment results indicated that the fouling resistance was significantly improved for the PVDF/GO-lysine membranes. As a result, lysine functionalized GO will provide a promising method to fabricate graphene oxide based hybrid membranes with effective antifouling property and hydrophilicity.
- PVDF membrane,
- Graphene oxide,
- Amino acids,
- Hydrophilicity,
- Antifouling property
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