Citation: Di-zheng Liu, Wei-lin Sun, Rong Ren, Yan-hua Wang, Zhi-quan Shen. Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd³⁺)[J]. Chinese Journal of Polymer Science, ;2016, 34(7): 910-918. doi: 10.1007/s10118-016-1804-6 shu

Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd³⁺)

MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Zhi-quan Shen, opl_sunwl@zju.edu.cn
Received Date: 31 January 2016
Revised Date: 9 March 2016
Accepted Date: 14 March 2016

Fund Project: This work was financially supported by the National Natural Science Foundation of China 21174129

Homopolymer (PBIP) containing 2, 6-bis(1'-methylbenzimidazolyl)pyridine (MeBIP) ligands in the side chain was synthesized by RAFT polymerization and its kinetics was studied. Polymeric complex PBIP-Nd³⁺ was prepared by chelating PBIP with lanthanide ion Nd³⁺. The homopolymers and PBIP-Nd³⁺ complex were investigated by NMR, FTIR, GPC and TGA. The optical property of PBIP-Nd³⁺ complex was characterized by UV-Vis spectroscopy. The magnetic property of PBIP-Nd³⁺ complex was measured as a function of temperature (5 K to 300 K) and as a function of field (-3.98 × 10⁶ A/m to 3.98 × 10⁶ A/m). These results indicated that PBIP-Nd³⁺ complex is paramagnetic.
- 2, 6-Bis(1'-methylbenzimidazolyl)pyridine,
- Magnetic,
- RAFT,
- Polymeric complex,
- Neodymium
1. [1]
  Ungur, L., Lin, S.Y., Tang, J.K. and Chibotarub, L.V., Chem. Soc. Rev., 2014, 43(20): 6894
2. [2]
  Zhang, P., Guo, Y.N. and Tang, J.K., Coord. Chem. Rev., 2013, 257(11-12): 1728
3. [3]
  Guo, Y.N., Xu, G.F., Wernsdorfer, W., Ungur, L., Guo, Y., Tang, J.K., Zhang, H.J., Chibotaru, L.F. and Powell, A.K., J. Am. Chem. Soc., 2011, 133(31): 11948
4. [4]
  Guo, Y.N., Xu, G.F., Gamez, P., Zhao, L., Lin, S.Y., Deng, R.P., Tang, J.K. and Zhang, H.J., J. Am. Chem. Soc., 2010, 132(25): 8538
5. [5]
  Karaagac, D. and Kurkcuoglu, G.S., J. Mol. Struct., 2016, 1105: 263
6. [6]
  Tartaj, J., Gil, V. and Moure, A., J. Power Sources, 2010, 195(9): 2800
7. [7]
  Zhang, P., Zhang, L., Wang, C., Xue, S., Lin, S.Y. and Tang, J.K., J. Am. Chem. Soc., 2014, 136(12): 4484
8. [8]
  Guo, Y.N., Ungur, L., Granroth, G.E., Powell, A.K., Wu, C., Nagler, S.E., Tang, J.K., Chibotaru, L.F. and Cui, D., Sci. Rep., 2014, 4: 5471
9. [9]
  Lin, S.Y., Wernsdorfer, W., Ungur, L., Powell, A.K., Guo, Y.N., Tang, J.K., Zhao, L., Chibotaru, L.F. and Zhang, H.J., Angew. Chem. Int. Ed. Engl., 2012, 51(51): 12767
10. [10]
  Guo, Y.N., Xu, G.F., Guo, Y. and Tang, J.K., Dalton Trans., 2011, 40(39): 9953
11. [11]
  Sugano, T., Tamura, M. and Kinoshita, M., Synth. Met., 1993, 56(2): 3305
12. [12]
  Miyasaka, H., Madanbashi, T., Sugimoto, K., Nakazawa, Y., Wernsdorfer, W., Sugiura, K.I., Yamashita, M., Coulon, C. and Clerac, R., Chem. Eur. J., 2006, 12(27): 7029
13. [13]
  Zheng, R.H., Jiang, H.J., Guo, H.C. and Sun, W.L., Acta Polymerica Sinica (in Chinese), 2011, (5): 435
14. [14]
  Zhou, X., Sun, W.L. and Shen, Z.Q., Acta Polymerica Sinica (in Chinese), 2014, (9): 1251
15. [15]
  Ding, N.W., Sun, W.L., Lin, Y. and Shen, Z.Q., Chinese J. Polym. Sci., 2012, 30(5): 759
16. [16]
  Jiang, H.J., Sun, W.L. and Zheng, R.H., Chinese J. Polym. Sci., 2006, 24(1): 81
17. [17]
  Yang, J., Lin, W.H., Sun, W.L., Jiang, H.J. and Shen, Z.Q., Chinese J. Polym. Sci., 2009, 27(1): 131
18. [18]
  Miller, J.S., and Epstein, A.J., MRS Bulletin, 2000, 25(11): 21
19. [19]
  Maclachlan, M.J., Aroca, P., Coombs, N. and Manners, I., Adv. Mater., 1992, 4: 612
20. [20]
  Lai, H.Q., Zhao, Z.N., Li, L.L., Zheng, W.J. and Chen, T.F., Metallomics, 2015, 7(3): 439
21. [21]
  Chao, S.J., Bai, Z.Y., Cui, Q., Yan, H.Y., Wang, K. and Yang, L., Carbon, 2015, 82: 77
22. [22]
  Li, Z.Q., Hou, Z.H., Ha, D.H. and Li, H.R., Asian J. Chem., 2015, 10(12): 2720
23. [23]
  Yang, W.W. and Zhong, Y.W., Chin. J. Chem., 2013, 31(3): 329
24. [24]
  Zhang, D.P., Zhuo, S.P., Zhang, H.Y., Wang, P. and Jiang, J.Z., Dalton Trans., 2015, 44(10): 4655
25. [25]
  Jeon, L.R., Calancea, S., Panja, A., Pinero Cruz, D.M., Koumousi, E.S., Dechambenoit, P., Coulon, C., Wattiaux, A., Rosa, P., Mathoniere, C. and Clerac, R., Chem. Sci., 2013, 4(6): 2463
26. [26]
  Qian, J., Hu, J.C., Yoshikawa, H., Zhang, J.F., Awaga, K. and Zhang, C., Eur. J. Inorg. Chem., 2015, 2015(12): 2110
27. [27]
  Panja, A., Guionneau, P., Jeon, I.R., Holmes, S.M., Clerac, R. and Mathoniere, C., Inorg. Chem., 2012, 51(22): 12350
28. [28]
  Nihei, M., Okamoto, Y., Sekine, Y., Hoshino, N., Shiga, T., Liu, I.P.C. and Oshio, H., Angew. Chem., 2012, 51(26): 6361
29. [29]
  Wang, Z.H., Fan, W.R., Tong, R., Lu, X.L. and Xia, H.S., RSC Adv., 2014, 4: 25486
30. [30]
  Chong, Y.K., Moad, G., Rizzardo, E. and Thang, S.H., Macromolecules, 2007, 40(13): 4446
31. [31]
  Piguet, C., Williams, A.F., Bernardiuelli, G., Moret, E. and Biinzli, J.C., Helv. Chim. Acta, 1992, 75: 1697
32. [32]
  An, H.Y., Han, Z.B. and Xu, T.Q., Inorg. Chem., 2010, 49(24): 11403
33. [33]
  Lhoste, J., Perez-Campos, A., Henry, N., Loiseau, T., Rabu, P. and Abraham, F., Dalton Trans, 2011, 40(36): 9136
34. [34]
  Ke, H.S., Zhao, L., Xu, G.F., Guo, Y.N., Tang, J.K., Zhang, X.Y. and Zhang, H.J., Dalton Trans., 2009, (47): 10609
35. [35]
  Andruh, M., Bakalbassis, E., Kahn, O., Trombe, J.C. and Porchers, P., Inorg. Chem., 1993, 32: 1616
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd3+)

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd³⁺)