Citation: Bin Liu, Fang-lin Huang, Yong-feng Shi, Zhi-qing Ni, Ye Lin, Shou-chun Yin. Synthesis, Characterization and Optical Properties of Poly(aryleneethynylene)s Containing BODIPY[J]. Chinese Journal of Polymer Science, ;2015, 33(8): 1133-1139. doi: 10.1007/s10118-015-1664-5 shu

Synthesis, Characterization and Optical Properties of Poly(aryleneethynylene)s Containing BODIPY

Bin Liu ^1,2,3 ,
Fang-lin Huang ⁴ ,
Yong-feng Shi ⁵ ,
Zhi-qing Ni ⁵ ,
Ye Lin ⁵ ,
Shou-chun Yin ^4,,

1.
1. Hangzhou Science and Technology Information Institute, Hangzhou 310001, China
2.
2. College of Material Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 310036, China
3.
4.
College of Material Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 310036, China
5.
Hangzhou Science and Technology Information Institute, Hangzhou 310001, China

Corresponding author: Shou-chun Yin,
Received Date: 29 November 2014
Revised Date: 31 December 2014

Fund Project: The work was financially supported by the National Natural Science Foundation of China (Nos. 21174035 and 21274034).

Poly(aryleneethynylene)s containing BODIPY (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) (P1) were prepared by palladium-catalyzed Sonogashira polymerization of 2,6-diiodo-functionalized BODIPY monomer (M1) with 1,4-diethynyl-2,5-didodecyl-oxybenzene monomer (M2). The structures of the monomer (M1) and copolymer (P1) were confirmed by 1H-NMR and Fourier transform infrared (FTIR) spectroscopies; their optical properties were characterized by UV-Vis absorption, photoluminescence (PL) spectroscopy and the Z-scan technique. Both UV-Vis absorption and fluorescence emission of copolymer P1 red-shifted to longer wavelengths (abs: from 502 nm to 542 nm; em: from 511 nm to 631 nm) relative to those of the monomer M1 due to the -conjugation extension of the copolymer. The third-order nonlinear optical coefficient ((3)) of copolymer P1 was 1.9410-10 esu, which is almost two or three orders of magnitude greater than that of common conjugated polymers without BODPIY moiety.
- BODIPY,
- Conjugated polymers,
- Nonlinear optics,
- Synthesis
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