Citation: Qi Wu, Wei Huang, Hai-jiang Wang, Li-li Pan, Chao-liang Zhang, Xi-kui Liu. Reversely Swellable Porphyrin-linked Microporous Polyimide Networks with Super-adsorption for Volatile Organic Compounds[J]. Chinese Journal of Polymer Science, ;2015, 33(8): 1125-1132. doi: 10.1007/s10118-015-1661-8 shu

Reversely Swellable Porphyrin-linked Microporous Polyimide Networks with Super-adsorption for Volatile Organic Compounds

1.
College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China
2.
West China Hospital of Stomatology, Sichuan University, Chengdu 610041, China

Corresponding author: Xi-kui Liu,
Received Date: 27 November 2014
Revised Date: 14 January 2015

Fund Project: This work was financially supported by the National Natural Science Foundation of China (Nos. 20974069 and 21174089), and the State Key Laboratory of Molecular Engineering of Polymers (Fudan University) (No. K2013-23).

A series of microporous polyimide networks with porphyrin units (Pr-MPIs) were facilely synthesized through a one-step solution polymerization process. Of particular interest is that Pr-MPI-1 containing distorted spirobisindane unit revealed the highest BET surface area (953 m2/g), total pore volume (0.75 cm3/g), and extreme hysteresis between the N2 adsorption and desorption isotherm. Further study revealed the prepared Pr-MPI-1 exhibited a synergistic structural effect on exceptional uptake of volatile organic compounds (VOCs) due to the high porosity and highly distorted spirobisindane structure enabled large interface and the swellability. This new approach would open up a facile approach toward the preparation of highly swellable high performance polymeric microporous materials, which are deeply wanted for environment-related applications such as VOCs adsorption and oil/water separation.
- Microporous polyimides,
- Spirobisindane,
- Swellability,
- Adsorption
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