Citation: Ming Li, Li-fen Zhang, Mei-xia Tao, Zhen-ping Cheng, Xiu-lin Zhu. Photo-induced Living Cationic Copolymerization of Isobutyl Vinyl Ether and Vinyl Ether with Carbazolyl Groups[J]. Chinese Journal of Polymer Science, ;2014, 32(11): 1564-1574. doi: 10.1007/s10118-014-1540-8 shu

Photo-induced Living Cationic Copolymerization of Isobutyl Vinyl Ether and Vinyl Ether with Carbazolyl Groups

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Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

Received Date: 27 January 2014
Revised Date: 25 March 2014

Fund Project: This work was financially supported by the National Natural Science Foundation of China (Nos. 21174096, 21274100 and 21234005), the Project of International Cooperation of the Ministry of Science and Technology of China (No. 2011DFA50530), and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

In this work, a fluorescent monomer 2-(9-carbazolyl) ethyl vinyl ether (CEVE) was synthesized in our lab, and its photo-induced living cationic copolymerization behavior with isobutyl vinyl ether (IBVE) was investigated in detail using diphenyliodonium chloride (DPICl)/2, 2-dimethoxy-2-phenylacetophenone (DMPA) and zinc bromide (ZnBr2) initiating system in dichloromethane solution at 5℃, -5℃, and -15℃, respectively. The living nature of this copolymerization system was confirmed by adding fresh comonomer method after the copolymerization almost finished. In addition, the obtained fluorescent copolymer poly(IBVE-co-CEVE) has a low glass transition temperature (Tg), below -10℃.
- Photopolymerization,
- Kinetics (polym.),
- Copolymerization,
- Cationic polymerization,
- Living cationic polymerization
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
1. [1]
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