Citation: Lei Zhang, Yong Guo, Wen-hao Chi, He-guang Shi, Hong-qi Ren, Tian-ying Guo. Electrospun Nanofibers Containing p-Nitrophenol Imprinted Nanoparticles for the Hydrolysis of Paraoxon[J]. Chinese Journal of Polymer Science, ;2014, 32(11): 1469-1478. doi: 10.1007/s10118-014-1530-x shu

Electrospun Nanofibers Containing p-Nitrophenol Imprinted Nanoparticles for the Hydrolysis of Paraoxon

1.
Key Laboratory of Functional Polymer Materials (Nankai University), Ministry of Education, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071, China

Corresponding author: Tian-ying Guo,
Received Date: 3 January 2014
Revised Date: 13 March 2014

Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 50978138), PCSIRT (IRT1257) and NFFTBS (No. J1103306).

p-Nitrophenol imprinted nanoparticles with a size range of 150-300 nm in diameter were prepared through miniemulsion polymerization. The imprinted polymer exhibited higher adsorption capacity for p-nitrophenol than the non-imprinted polymer. The hydrolysis of paraoxon in aqueous phase can be accelerated in the presence of the p-nitrophenol imprinted nanoparticles. The hydrolysis rate of paraoxon incorporated with the imprinted nanoparticles was 2.8310-7 mol/(Lmin), which was about 3.7 times higher compared to the non-imprinted nanoparticles, 12.7 times higher to the spontaneous hydrolysis. The nanoparticles have been mixed with polyacrylonitrile solution and electrospun into nanofibers, which can also be used to accelerate the hydrolysis of paraoxon and conveniently separated from liquid phase for further processing.
- Molecular imprinting,
- Electrospining,
- Nanofiber,
- 4-Nitrophenol,
- Paraoxon
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