Citation: Mohammad Ali, Karimi Zarchi, Ali Tarabsaz. A VERSATILE AND REGIOSELECTIVE SYNTHESIS OF VICINAL AZIDOALCOHOLS USING CROSS-LINKED POLY(4-VINYLPYRIDINE) SUPPORTED AZIDE ION UNDER SOLVENT-FREE CONDITIONS[J]. Chinese Journal of Polymer Science, ;2013, 31(12): 1660-1669. doi: 10.1007/s10118-013-1362-0 shu

A VERSATILE AND REGIOSELECTIVE SYNTHESIS OF VICINAL AZIDOALCOHOLS USING CROSS-LINKED POLY(4-VINYLPYRIDINE) SUPPORTED AZIDE ION UNDER SOLVENT-FREE CONDITIONS

1.
Department of Chemistry, College of Science, Yazd University, Yazd, Iran

Corresponding author: Karimi Zarchi,
Received Date: 4 January 2013
Revised Date: 4 February 2013

A new polymeric reagent, cross-linked poly(4-vinylpyridine) supported azide ion, [P4-VP]N3, was introduced as polymeric reagents for efficient and regioselective conversion of epoxides to azidohydrins in the presence of cross-linked poly(4-vinylpyridine) supported sulfuric acid, [P4-VP]H2SO4, as a solid proton source and as catalyst under solvent-free conditions. The advantages of this polymeric reagent over some of those reported in the literature are easy work-up procedure and regeneration of the reagent.
- Ring opening of epoxide,
- -Azidoalcohols,
- Poly(4-vinylpyridine),
- Solvent-free conditions,
- Regioselectivity
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