Citation: Xiao-hua Huang, Wei Huang, Yong-feng Zhou, De-yue Yan. SYNTHESIS AND CHARACTERIZATION OF HIGHLY SOLUBLE AROMATIC POLYIMIDES[J]. Chinese Journal of Polymer Science, ;2011, 29(4): 506-512. doi: 10.1007/s10118-011-1058-2 shu

SYNTHESIS AND CHARACTERIZATION OF HIGHLY SOLUBLE AROMATIC POLYIMIDES

Received Date: 23 August 2010
Revised Date: 19 October 2010

Two highly soluble aromatic polyimides were synthesized successfully from a diamine with two tert-butyl groups (MBTBA) and dianhydrides with a thioether or sulfone moiety (DTDA and DSDA). Both of them showed excellent solubility in common solvents such as chloroform, tetrahydrofuran and dioxane at the room temperature. The number-average molecular weight was 6.0 104 and 8.3 104 according to gel permeation chromatography relative to a polystyrene standard, and the polydispersity index was 1.80 and 1.82 respectively. The glass-transition temperatures of them were 286C and 314C (or 315C and 358C) respectively, as measured by differential scanning calorimetry (or dynamic mechanical analysis). The 5% weight loss temperature of both was near 490C in N2 by thermogravimetric analysis. These results indicated that the tert-butyl pendent groups reduced the interactions among polymer chains and the thioether or sulfone moiety was flexible which may improve their solubility in conventional organic solvents without the loss of thermal stability. Transparent and flexible films of the two polyimides were obtained via solution casting. The MBTBA-DTDA membrane had higher storage moduli than those of the MBTBA-DSDA membrane.
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沈阳化工大学材料科学与工程学院沈阳 110142