Preparation and triethylamine sensing performance of ZnSnO3/NiO heterostructur
Liyong DU, Yi LIU, Guoli YANG
【无机化学学报】doi: 10.11862/CJIC.20240404
In this study, ZnSnO3/NiO heterostructures were synthesized using a co-precipitation method followed by an annealing process. The gas-sensitive characteristics of the sensors based on these samples were evaluated. The results indicate that the sensor performance was optimized when the molar ratio of Ni to Zn was 1∶2. Specifically, the response values of the ZnSnO3/NiO-2-based sensor to 100 μL·L-1 triethylamine (TEA) gas at 220 ℃ reached 70.6, which were 6.1 times higher than that of the pure ZnSnO3 based sensor. The findings demonstrate that ZnSnO3/NiO heterostructures exhibited not only short response and recovery times (1 s/18 s) but also good gas selectivity, repeatability, and long-term stability. The enhanced sensing mechanism has been investigated in detail.
关键词: heterostructures, ZnSnO3/NiO, triethylamine, gas sensing performance, gas sensing mechanism
面向化学类非高分子专业学生的高分子化学实验教学创新与实践——以温型高分子的制备、溶液性质、光学性能与应用为例
张来英, 吴莹焕, 喻雅姿, 徐业成, 张豪杰, 吴伟泰
【大学化学】doi: 10.3866/PKU.DXHX202310126
面向化学类(非高分子)专业的高分子化学实验教学发展较为缓慢,亟需紧跟研究前沿,引入新内容。本文总结了近十年的教学改革经验,并以温敏型高分子的制备、溶液性质、光学性能与应用为例,介绍如何通过实验教学内容、实验技术、教学方法等方面的创新,设计符合理科人才培养需求的、契合时代与科学发展的、被学生喜爱与重视的一系列高分子化学实验,以有效解决培养需求与课业负担之间的矛盾,且在不新增开课、课时有限的情况下,加入到化学类专业本科教学体系中,激发学生对学科领域的兴趣,提升学生的探究和创新能力。
关键词: 高分子化学, 实验教学, 智能高分子, 聚合, 综合性实验
科产教融合下“现代分析技术”课程改革与实践
温聪颖, 杜正坤, 卢玉坤, 王宗廷, 何化, 杨丽敏, 曾景斌
【大学化学】doi: 10.3866/PKU.DXHX202312089
本文在科产教融合理念下,对“现代分析技术”进行了课程改革。主要基于校内/际/企合作实现优质师资共享,通过融入科学前沿和生产实际丰富教学内容,在授课中采用教师主导、学生自主探究、“理虚实”结合、线上线下协同、公众号辅助等多维教学模式,同时配备多元化考核评价体系促学促教。实践结果表明,教学质量得到了明显提升,极大地助力于理论知识、科学研究、生产实践兼顾兼优的复合型人才的培养。
关键词: 现代分析技术, 教学改革, 科产教融合, 复合型人才

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