【大学化学】doi: 10.3866/PKU.DXHX202312089
本文在科产教融合理念下,对“现代分析技术”进行了课程改革。主要基于校内/际/企合作实现优质师资共享,通过融入科学前沿和生产实际丰富教学内容,在授课中采用教师主导、学生自主探究、“理虚实”结合、线上线下协同、公众号辅助等多维教学模式,同时配备多元化考核评价体系促学促教。实践结果表明,教学质量得到了明显提升,极大地助力于理论知识、科学研究、生产实践兼顾兼优的复合型人才的培养。
【无机化学学报】doi: 10.11862/CJIC.20240431
Hydroxyapatite nanoparticles (HAP NPs) were synthesized by a one‐step hydrothermal method. The surface of HAP NPs was grafted —SH and —COOH chelating groups via in situ surface‐modification with iminodiacetic acid (IDA) and 3‐mercaptopropyl trimethoxysilane (MPS) to afford dual surface‐capped nano‐amendment HAP‐IDA/MPS. The structure of HAP‐IDA/MPS was characterized, and its adsorption performance for Hg2+, Cu2+, Zn2+, Ni2+, Co2+, and Cd2+ was evaluated. The total adsorption capacity of 0.10 g HAP‐IDA/MPS nano‐amendment for Hg2+, Cu2+, Zn2+, Ni2+, Co2+, and Cd2+ with an initial mass concentration of 20 mg·L-1 reached 13.7 mg·g-1, about 4.3 times as much as that of HAP. Notably, HAP‐IDA/MPS nano‐amendment displayed the highest immobilization rate for Hg2+, possibly because of its chemical reaction with —SH to form sulfide, possessing the lowest solubility product constant among a variety of metal sulfides.