Small-size Au nanoparticles anchored on pyrenyl-graphdiyne for N2 electroreduction
Chang LIU, Chao ZHANG, Tongbu LU
【无机化学学报】doi: 10.11862/CJIC.20240305
A gold catalyst of Au/ pyrenyl-graphdiyne (Pyr-GDY) was prepared by anchoring small size of gold nanoparticles (Au NPs) on the surface of Pyr-GDY for electrocatalytic nitrogen reduction reaction (eNRR), in which Au NPs with a size of approximately 3.69 nm was evenly distributed on spongy-like porous Pyr-GDY. The catalyst exhibited a good electrocatalytic activity for N2 reduction in a nitrogen-saturated electrolyte, with an ammonia yield of 32.1 μg·h-1·mgcat-1 at -0.3 V (vs RHE), 3.5 times higher than that of Au/C (Au NPs anchored on carbon black). In addition, Au/Pyr-GDY showed a Faraday efficiency (FE) of 26.9% for eNRR, and a good catalysis durability for over 22 h.
关键词: graphdiyne, small-size Au nanoparticle, electrocatalytic nitrogen reduction
人工智能在高分子化学教学中的应用——革新、实践与隐忧
胡浩, 刘畅, 郭霖, 袁华, 黄林军
【大学化学】doi: 10.12461/PKU.DXHX202503010
随着人工智能(AI)迅猛发展,高分子化学教学迎来了诸多革新机遇,却也面临一系列挑战。本文深度剖析AI在教学内容、方法、课堂模式以及师生角色转变等方面的创新实践,并探讨其面临的问题。通过实际案例提出提升教师素养、完善教学资源建设等应对策略,旨在推动AI与高分子化学教学深度融合,全方位提升教学质量。
关键词: 智能教学工具, 高分子化学, 教学革新, 教学实践, 技术局限

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