Facile synthesis of gold nanoplates by thermally reducing AuCl<sub>4</sub><sup>-</sup> with aniline

引用本文: Kang Xu, Zhi rui Guo, Ning Gu. Facile synthesis of gold nanoplates by thermally reducing AuCl₄^- with aniline[J]. Chinese Chemical Letters, 2009, 20(2): 241-244. doi: 10.1016/j.cclet.2008.10.053 shu

Citation: Kang Xu, Zhi rui Guo, Ning Gu. Facile synthesis of gold nanoplates by thermally reducing AuCl₄^- with aniline[J]. Chinese Chemical Letters, 2009, 20(2): 241-244. doi: 10.1016/j.cclet.2008.10.053 shu

Facile synthesis of gold nanoplates by thermally reducing AuCl₄^- with aniline

a State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096, China;
b Jiangsu Laboratory for Biomaterials and Devices, Southeast University, Nanjing 210096, China;
c School of Chemistry and Chemical engineering, Southeast University, Nanjing 210096, China
基金项目:
This work was supported by the National Natural Science Foundation of China (Nos. 90406023, 60571031 and 60501009) and the National Important Science Research Program of China (No. 2006CB933206).

摘要: We herein report a one-step, wet-chemical approach to synthesizing gold nanoplates in large quantities via the AuCl₄^- thermal reduction process by aniline, without introducing additional capping agent or surfactant. It is found that the reduction kinetics of AuCl₄^- is greatly altered by varying the initial molar ratio of aniline to AuCl₄^-. Moreover, further investigation reveals that the insitu formed polyaniline could serve effectively as a capping agent to preferably adsorb the {111} facets of gold crystals during a slow reduction process, directing the formation of gold nanoplates.

关键词:

English

Facile synthesis of gold nanoplates by thermally reducing AuCl₄^- with aniline

a State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096, China;
b Jiangsu Laboratory for Biomaterials and Devices, Southeast University, Nanjing 210096, China;
c School of Chemistry and Chemical engineering, Southeast University, Nanjing 210096, China
Received Date: 19 June 2008
Fund Project:
This work was supported by the National Natural Science Foundation of China (Nos. 90406023, 60571031 and 60501009) and the National Important Science Research Program of China (No. 2006CB933206).

Abstract: We herein report a one-step, wet-chemical approach to synthesizing gold nanoplates in large quantities via the AuCl₄^- thermal reduction process by aniline, without introducing additional capping agent or surfactant. It is found that the reduction kinetics of AuCl₄^- is greatly altered by varying the initial molar ratio of aniline to AuCl₄^-. Moreover, further investigation reveals that the insitu formed polyaniline could serve effectively as a capping agent to preferably adsorb the {111} facets of gold crystals during a slow reduction process, directing the formation of gold nanoplates.

Key words:

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 812
HTML全文浏览量: 2

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Facile synthesis of gold nanoplates by thermally reducing AuCl₄^- with aniline

English

Facile synthesis of gold nanoplates by thermally reducing AuCl₄^- with aniline

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Facile synthesis of gold nanoplates by thermally reducing AuCl4- with aniline

English

Facile synthesis of gold nanoplates by thermally reducing AuCl4- with aniline

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Facile synthesis of gold nanoplates by thermally reducing AuCl₄^- with aniline

Facile synthesis of gold nanoplates by thermally reducing AuCl₄^- with aniline

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs