联苯-联苯醚混合萃取剂分散液液微萃取测定饮用水中挥发性卤代烃

引用本文: 杜小弟, 蔡宏伟, 郭丽萍, 雷家珩. 联苯-联苯醚混合萃取剂分散液液微萃取测定饮用水中挥发性卤代烃[J]. 分析化学, 2018, 46(9): 1493-1500. doi: 10.11895/j.issn.0253-3820.181176 shu

Citation: DU Xiao-Di, CAI Hong-Wei, GUO Li-Ping, LEI Jia-Heng. Determination of Volatile Halogenated Hydrocarbon in Drinking Water Using Dispersive Liquid-Liquid Microextraction with Biphenyl-Biphenyl Ether Mixture as Extractants[J]. Chinese Journal of Analytical Chemistry, 2018, 46(9): 1493-1500. doi: 10.11895/j.issn.0253-3820.181176 shu

联苯-联苯醚混合萃取剂分散液液微萃取测定饮用水中挥发性卤代烃

武汉理工大学化学化工与生命科学学院化学系, 武汉 430070
基金项目:
本文系国家自然科学基金项目（No.21476177）资助

摘要: 以联苯-联苯醚混合物为萃取剂，建立了分散液液微萃取-气相色谱电子捕获检测器测定饮用水中7种挥发性卤代烃的方法。此萃取剂为无卤素萃取剂，密度大于水，可通过离心分离，萃取过程可在3 min内完成。对萃取剂用量、分散剂种类及用量、萃取时间、萃取温度等条件进行了优化。5.00 mL水样用200 μL萃取剂和0.30 mL分散剂（甲醇）的混合物进行萃取，室温下萃取30 s，7种挥发性卤代烃的萃取率≥90%，富集倍率为22.5~24.7。萃取液经DB-624毛细管柱分离，用电子捕获检测器定量检测，检出限为0.003~0.032 μg/L。检测三氯甲烷的线性范围为0.500~100.0 μg/L，三氯乙烯和三溴甲烷的线性范围为0.100~20.0 μg/L，四氯化碳、四氯乙烯、二氯一溴甲烷、一氯二溴甲烷的线性范围为0.050~10.0 μg/L。在上述线性范围内，工作曲线的相关系数≥0.998。方法的相对标准偏差在2.1%~7.6%之间，加标回收率在93.0%~102.9%之间。

关键词:

English

Determination of Volatile Halogenated Hydrocarbon in Drinking Water Using Dispersive Liquid-Liquid Microextraction with Biphenyl-Biphenyl Ether Mixture as Extractants

Department of Chemistry, School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, China
Received Date: 20 March 2018
Revised Date: 08 May 2018
Fund Project:
This work was supported by the National Natural Science Foundation of China (No. 21476177).

Abstract: A method for determination of seven volatile halogenated hydrocarbons in drinking water by dispersive liquid-liquid microextraction-gas chromatography with electron capture detection was developed. Biphenyl-biphenyl ether mixture, as a non-chlorinated organic solvent, was used as extractant. The extractant could be separated easily by centrifugation because of its high density, and the extraction process could be completed within 3 min. The amount of extractants, types and amount of dispersants, extraction time and extraction temperature were optimized. For the extraction of seven volatile halogenated hydrocarbons from 5.00 mL aqueous sample, 200 μL of extractant and 0.30 mL of methanol as disperser solvent were used, and the extraction equilibrium could be reached within 30 s with a high extraction recovery of over 90%. In addition, the enrichment factor reached a high value of 22.5-24.7. The sediment phase was injected and analyzed by gas chromatography with DB-624 column and detected by electron capture detector. The limit of detection of this method was 0.003-0.032 μg/L based on S/N=3. The linear range for chloroform was from 0.500 μg/L to 100.0 μg/L, for trichloroethylene and bromoform was from 0.100 μg/L to 20.0 μg/L, for perchlormethane, bromodichloromethan, dibromochloromethane and perchloroethylene was from 0.100 μg/L to 10.0 μg/L, while the correlation coefficients (R²) were no less than 0.998. The relative standard deviations of this method were 2.1%-7.6%. At different concentration levels, the relative recoveries ranged from 93.0% to 102.9%.

Key words:

Gas chromatography
/ Dispersive liquid-liquid microextraction
/ Non-chlorinated extractant
/ Volatile halogenated hydrocarbon
/ Disinfection byproducts
/ Drinking water

1. [1]
  Richardson S D. TrAC-Trend. Anal. Chem.,2003,22(10):666-684
2. [2]
  Liew D, Linge K L, Joll C A. Environ. Monit. Assess.,2016,188(9):518
3. [3]
  Guidelines for Drinking Water Quality. 4th ed., World Health Organization,2011
4. [4]
  GB 5749-2006. Standard for Drinking Water Quality. National Standards of the People's Republic of China 生活饮用水卫生标准.中华人民共和国国家标准. GB 5749-2006.
5. [5]
  Kanchanamayoon W. Chromatographia,2015,78(17-18):1135-1142
6. [6]
  LEI Jia-Heng, WU Qiong, DU Xiao-Di, ZHOU Hua. PTCA (PART B:Chem. Anal.),2016,52(3):255-258 雷家珩, 吴琼, 杜小弟, 周华.理化检验:化学分册,2016,52(3):255-258
7. [7]
  HJ 620-2011. Water Quality-Determination of Volatile Halogenated Organicconpounds-Headspace Gas Chromatography. Environmental Protection Standards of the People's Republic of China 水质挥发性卤代烃的测定顶空气相色谱法.中华人民共和国国家环境保护标准. HJ 620-2011
8. [8]
  Determination of Chlorination Disinfection Byproducts, Chlorinated Solvents, and Halogenated Pesticides/Herbicides in Drinking Water by Liquid-Liquid Extraction and Gas Chromatography with Electron-Capture Detection. United States Environmental Protection Agency 551.1,1995
9. [9]
  Villanueva C M, Kogevinas M, Grimalt J O. Water Res.,2003,37(4):953-958
10. [10]
  HUANG Yi, RAO Zhu, WANG Chao. Journal of Instrumental Analysis,2012,31(6):705-709 黄毅, 饶竹, 王超.分析测试学报,2012,31(6):705-709
11. [11]
  Maia R, Correia M, Pereira I M B, Beleza V M. Microchem. J.,2014,112:164-171
12. [12]
  ZHANG Zhong-Xiang, ZHAO Qi, LIU Yu-Lei, MA Jun, QI Jing-Yao, REN Zhi-Jun. Chinese J. Anal. Chem.,2017,45(8):1203-1208 张忠祥, 赵琦, 刘玉蕾, 马军, 齐晶瑶, 任芝军.分析化学,2017,45(8):1203-1208
13. [13]
  Montesinos I, Gallego M. J. Chromatogr. A,2012,1248:1-8
14. [14]
  Rezaee M, Assadi Y, Hosseini M R M, Aghaee E, Ahmadi F, Berijani S. J. Chromatogr. A,2006,1116(1-2):1-9
15. [15]
  Agnieszka Z G, Tomasz G. TrAC-Trend. Anal. Chem.,2011,30(9):1382-1399
16. [16]
  Yan H, Wang H. J. Chromatogr. A,2013,1295:1-15
17. [17]
  Campillo N, Viñas P, Sandrejová J, Andruch V. Appl. Spectrosc. Rev.,2017,52(4):267-415
18. [18]
  Kozani R R, Assadi Y, Shemirani F, Hosseini M R M, Jamali M R. Chromatographia,2007,66(1-2):81-86
19. [19]
  Ma H, Li Y, Zhang H, Shah S M, Chen J. J. Chromatogr. A,2014,1358:14-19
20. [20]
  Leong M I, Fuh M R, Huang S D. J. Chromatogr. A,2014,1335:2-14
21. [21]
  Rodríguez-Cabo T, Ramil M, Rodríguez I, Cela R. Talanta,2012,99(18):846-852
22. [22]
  Idaira P F, Ariadna H F, Bárbara D, Verónica P, Juan H A, Ana M A. Environmen. Technol. Lett.,2017,38(6):718-729

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联苯-联苯醚混合萃取剂分散液液微萃取测定饮用水中挥发性卤代烃

English

Determination of Volatile Halogenated Hydrocarbon in Drinking Water Using Dispersive Liquid-Liquid Microextraction with Biphenyl-Biphenyl Ether Mixture as Extractants

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

联苯-联苯醚混合萃取剂分散液液微萃取测定饮用水中挥发性卤代烃

English

Determination of Volatile Halogenated Hydrocarbon in Drinking Water Using Dispersive Liquid-Liquid Microextraction with Biphenyl-Biphenyl Ether Mixture as Extractants

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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