引用本文:
Jie Ying WU, Yu Peng TIAN, Fu Xin XIE, Shi Sheng NI. A Novel Biferrocene Trinuclear Complex with Cis-Configuration[J]. Chinese Chemical Letters,
1999, 10(3): 251-254.
Citation: Jie Ying WU, Yu Peng TIAN, Fu Xin XIE, Shi Sheng NI. A Novel Biferrocene Trinuclear Complex with Cis-Configuration[J]. Chinese Chemical Letters, 1999, 10(3): 251-254.
Citation: Jie Ying WU, Yu Peng TIAN, Fu Xin XIE, Shi Sheng NI. A Novel Biferrocene Trinuclear Complex with Cis-Configuration[J]. Chinese Chemical Letters, 1999, 10(3): 251-254.
A Novel Biferrocene Trinuclear Complex with Cis-Configuration
摘要:
A novel biferocene trinuclear complex for Schiff base ligand S-methyt-N-(ferrocenyll-methyl -methylidene) dithiocarbazate (hereafter abbreviated as HL) is described.X-ray diffraction studies established the structure of the palladium complex, PdL2.The geometry of Pd (Ⅱ) in the complex is close to square planar and in novel cis-configuration with two ferrocene moieties on the same side.Degenerate four-wave mixing (DFWM) measurements show that the complex exhibit obvious nonlinear optical response.
English
A Novel Biferrocene Trinuclear Complex with Cis-Configuration
Abstract:
A novel biferocene trinuclear complex for Schiff base ligand S-methyt-N-(ferrocenyll-methyl -methylidene) dithiocarbazate (hereafter abbreviated as HL) is described.X-ray diffraction studies established the structure of the palladium complex, PdL2.The geometry of Pd (Ⅱ) in the complex is close to square planar and in novel cis-configuration with two ferrocene moieties on the same side.Degenerate four-wave mixing (DFWM) measurements show that the complex exhibit obvious nonlinear optical response.
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