引用本文:
Shi Guo SUN, Xiao Jun PENG, Yong Qian XU, Lei SHI, Yun Ling GAO, Li Cheng SUN. Studies of a Series of Novel Rhenium(Ⅰ) Bipyridyl Dyes for Solar Cells[J]. Chinese Chemical Letters,
2005, 16(5): 677-680.
Citation: Shi Guo SUN, Xiao Jun PENG, Yong Qian XU, Lei SHI, Yun Ling GAO, Li Cheng SUN. Studies of a Series of Novel Rhenium(Ⅰ) Bipyridyl Dyes for Solar Cells[J]. Chinese Chemical Letters, 2005, 16(5): 677-680.
Citation: Shi Guo SUN, Xiao Jun PENG, Yong Qian XU, Lei SHI, Yun Ling GAO, Li Cheng SUN. Studies of a Series of Novel Rhenium(Ⅰ) Bipyridyl Dyes for Solar Cells[J]. Chinese Chemical Letters, 2005, 16(5): 677-680.
Studies of a Series of Novel Rhenium(Ⅰ) Bipyridyl Dyes for Solar Cells
摘要:
A series of novel rhenium(Ⅰ) 2,2'-bipyridyl complexes[fac-Re(4,4'-di-COOEt-bpy)-(CO)3(Xpy)PF6], where bpy is 2,2'-bipyridine, py is pyridine and X is 3-methyl, 3-hydroxy, or3-amino, were synthesized, their photophysical and electrochemical properties were studied. The Re(Ⅱ/Ⅰ) oxidation potentials decreased as the X group becomes more electron donating from H to3-methyl, 3-hydroxy, or 3-amino, which might be a very convenient ways for adjusting the electron transfer driving force.
English
Studies of a Series of Novel Rhenium(Ⅰ) Bipyridyl Dyes for Solar Cells
Abstract:
A series of novel rhenium(Ⅰ) 2,2'-bipyridyl complexes[fac-Re(4,4'-di-COOEt-bpy)-(CO)3(Xpy)PF6], where bpy is 2,2'-bipyridine, py is pyridine and X is 3-methyl, 3-hydroxy, or3-amino, were synthesized, their photophysical and electrochemical properties were studied. The Re(Ⅱ/Ⅰ) oxidation potentials decreased as the X group becomes more electron donating from H to3-methyl, 3-hydroxy, or 3-amino, which might be a very convenient ways for adjusting the electron transfer driving force.
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