引用本文:
Zhi Xian ZHOU, Yan Jun XING, Kui LU, Yang Jie WU. Synthesis and Crystal Structure of Complex of Sodium Perrhenate with Tetraethyl p-tert-Butylcalix [4] arene Tetraacetate[J]. Chinese Chemical Letters,
1998, 9(11): 1067-1068.
Citation: Zhi Xian ZHOU, Yan Jun XING, Kui LU, Yang Jie WU. Synthesis and Crystal Structure of Complex of Sodium Perrhenate with Tetraethyl p-tert-Butylcalix [4] arene Tetraacetate[J]. Chinese Chemical Letters, 1998, 9(11): 1067-1068.
Citation: Zhi Xian ZHOU, Yan Jun XING, Kui LU, Yang Jie WU. Synthesis and Crystal Structure of Complex of Sodium Perrhenate with Tetraethyl p-tert-Butylcalix [4] arene Tetraacetate[J]. Chinese Chemical Letters, 1998, 9(11): 1067-1068.
Synthesis and Crystal Structure of Complex of Sodium Perrhenate with Tetraethyl p-tert-Butylcalix [4] arene Tetraacetate
摘要:
The complex of sodium perrhenate with ester derivative of calix [4] arene having the stoichiometric formula [NaL]ReO4·H20, was prepared. The X-ray structure analysis revealed that the sodium ion is coordinated to four ether and four carbonyl oxygen atoms giving a coordination number of eight with a tetragonal antiprism configuration. The complex cation [NaL]+ and anion ReO4- are linked by electrostatic attraction.
English
Synthesis and Crystal Structure of Complex of Sodium Perrhenate with Tetraethyl p-tert-Butylcalix [4] arene Tetraacetate
Abstract:
The complex of sodium perrhenate with ester derivative of calix [4] arene having the stoichiometric formula [NaL]ReO4·H20, was prepared. The X-ray structure analysis revealed that the sodium ion is coordinated to four ether and four carbonyl oxygen atoms giving a coordination number of eight with a tetragonal antiprism configuration. The complex cation [NaL]+ and anion ReO4- are linked by electrostatic attraction.
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Key words:
- Calix [4] arene
- / sodium perrhenate, crystal structure
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