三维介孔钴酸锌立方体的制备及其优异的储锂性能

引用本文: 甄绪, 郭雪静. 三维介孔钴酸锌立方体的制备及其优异的储锂性能[J]. 物理化学学报, 2017, 33(4): 845-852. doi: 10.3866/PKU.WHXB201612222 shu

Citation: ZHEN Xu, GUO Xue-Jing. Synthesis and Lithium Storage Performance of Three-Dimensional Mesostructured ZnCo₂O₄ Cubes[J]. Acta Physico-Chimica Sinica, 2017, 33(4): 845-852. doi: 10.3866/PKU.WHXB201612222 shu

三维介孔钴酸锌立方体的制备及其优异的储锂性能

甄绪 ^2, ,
郭雪静 ^1,

1.
南开大学环境科学与工程学院, 天津 300071;
2.
61413部队, 湖北襄阳 441003
基金项目:
国家自然科学基金（12HZGJHZ01100）资助项目

摘要: 采用简易、温和、实际耐用的水热方法制备了新型三维介孔立方体结构的钴酸锌纳米材料。每个钴酸锌立方体的边长大约在3-4 μm之间，并由大量的纳米粒子和密集的孔隙所构成。通过氮吸附/脱附手段测试发现所制备的钴酸锌纳米材料具有较大的比表面积（41.4 m²·g^-1）和介孔（6.32 nm）特性。使用钴酸锌纳米材料作为锂离子电池负极，金属锂作为正极组装锂电池并测试了材料的储锂性能。研究发现该电极材料在较高的电流密度下循环100周后，仍能呈现较高的可逆容量和超强的循环稳定性。这种优异的储锂性能主要归因于钴酸锌纳米材料的新型结构，这种介孔立方体结构能够加速锂离子的扩散，增加电极与电解液的接触面积并缓解锂离子嵌入/嵌出期间产生的体积膨胀。

关键词:

English

Synthesis and Lithium Storage Performance of Three-Dimensional Mesostructured ZnCo₂O₄ Cubes

ZHEN Xu ^2, ,
GUO Xue-Jing ^1,

1.
College of Environmental Science and Engineering, Nankai University, Tianjin 300071, P. R. China;
2.
61413 Troops, Xiangyang 441003, Hubei Provnce, P. R. China
Received Date: 10 October 2017
Revised Date: 22 December 2016
Available Online: 22 December 2016
Fund Project:
The project was supported by the National Natural Science Foundation of China (12HZGJHZ01100).

Abstract: Novel three-dimensional (3D) mesostructured ZnCo₂O₄ cubes are prepared through a convenient and practical hydrothermal route combined with an annealing treatment. The as-prepared ZnCo₂O₄ cubes range from 3-4 μm in size, and are composed of a large number of nanoparticles and pores. According to N₂ adsorption-desorption measurements, the as-synthesized ZnCo₂O₄ cubes have a high BET surface area (41.4 m²·g^-1) and mesoporous (6.32 nm) nature. Lithium ion batteries (LIBs) are assembled using the as-prepared ZnCo₂O₄ nanomaterial and metallic lithium as the anode and the cathode, respectively, and their lithium storage performance is investigated. The electrode material exhibits highly reversible lithium storage capacity and strong cycling stability at high current density for 100 cycles. More importantly, the ZnCo₂O₄ cube electrode still presents a relatively high specific capacity at high rate. The excellent lithium storage performance is attributed to the novel structure of the 3D mesostructured cubes, which can facilitate Li⁺ diffusion, increase electrode/electrolyte contact area, and endure volume changes the during Li⁺ insertion/extraction process.

Key words:

1. [1]
  Tang, Y. P.; Yuan, S.; Guo, Y. Z.; Huang, R. A.; Wang, J. H.; Yang, B.; Dai, Y. N. Acta Phys. -Chim. Sin. 2016, 32, 2280. [唐艳平, 元莎, 郭玉忠, 黄瑞安, 王剑华, 杨斌, 戴永年. 物理化学学报, 2016, 32, 2280.] doi: 10.3866/PKU.WHXB201605124
2. [2]
  Tang, Z. Y.; Feng, J. J. Acta Phys. -Chim. Sin. 2003, 19, 1025.[唐致远, 冯季军. 物理化学学报, 2003, 19, 1025.] doi: 10.3866/PKU.WHXB20031108
3. [3]
  Gao, G. X.; Wu, H. B.; Ding, S. J.; Lou, X.W. Small 2015, 11, 432. doi: 10.1002/smll.201400152
4. [4]
  Bai, J.; Li, X.; Liu, G.; Qian, Y.; Xiong, S. Adv. Funct. Mater. 2014, 24, 3012. doi: 10.1002/adfm.201303442
5. [5]
  Wang, M.; Cheng, L. M.; Li, Q. B.; Chen, Z.W.; Wang, S. L. Phys. Chem. Chem. Phys. 2014, 16, 21742. doi: 10.1039/c4cp03407d
6. [6]
  Woo, M. A.; Kim, T.W.; Kim, I. Y.; Hwang, S. J. Solid State Ionics 2011, 182, 91. doi: 10.1016/j.ssi.2010.10.025
7. [7]
  Bresser, D.; Paillard, E.; Kloepsch, R.; Krueger, S.; Fiedler, M.; Schmitz, R.; Baither, D.; Winter, M.; Passerini, S. Adv. Energy Mater. 2013, 3, 513. doi: 10.1002/aenm.201200735
8. [8]
  Gao, G. X.; Wu, H. B.; Dong, B. T.; Ding, S. J.; Lou, X.W. Adv. Sci. 2015, 2, 1400014. doi: 10.1002/advs.201400014
9. [9]
  Zhou, L.; Wu, H. B.; Zhu, T.; Lou, X.W. J. Mater. Chem. 2012, 22, 827. doi: 10.1039/c1jm15054e
10. [10]
  Luo, W.; Hu, X. L.; Sun, Y. M.; Huang, Y. H. J. Mater. Chem. 2012, 22, 8916. doi: 10.1039/c2jm00094f
11. [11]
  Giri, A. K.; Pal, P.; Ananthakumar, R.; Jayachandran, M.; Mahanty, S.; Panda, A. B. Cryst. Growth Des. 2014, 14, 3352. doi: 10.1021/cg500282n
12. [12]
  Hao, S. J.; Zhang, B.W.; Ball, S.; Copley, M.; Xu, Z. C.; Srinivasan, M.; Zhou, K.; Mhaisalkar S.; Huang, Y. Z. J. Power Sources 2015, 294, 112. doi: 10.1016/j.jpowsour.2015.06.048
13. [13]
  Guo, L. Y.; Ru, Q.; Song, X.; Hu, S. J.; Mo, Y. D. RSC Adv. 2015, 5, 19241. doi: 10.1039/c4ra15553j
14. [14]
  Hung, T. F.; Mohamed, S. G.; Shen, C. C.; Tsai, Y. Q.; Chang, W. S.; Liu, R. S. Nanoscale 2013, 5, 12115. doi: 10.1039/c3nr04271e
15. [15]
  Liu, X. H.; Zhang, J.; Wang, L.W.; Yang, T. L.; Guo, X. Z.; Wu, S. H.; Wang, S. R. J. Mater. Chem. 2011, 21, 349. doi: 10.1039/c0jm01800g
16. [16]
  Hou, L.; Lian, L.; Zhang, L.; Pang, G.; Yuan, C.; Zhang, X. Adv. Funct. Mater. 2015, 25, 238. doi: 10.1002/adfm.201402827
17. [17]
  Li, J.; Xiong, S.; Li, X.; Qian, Y. Nanoscale 2013, 5, 2045. doi: 10.1039/c2nr33576j
18. [18]
  Zhang, C.; Huang, B.; Qian, L. H.; Yuan, S. L.; Wang, S.; Chen, R. ChemPhysChem 2016, 17, 98. doi: 10.1002/cphc.201500854
19. [19]
  Sun, L.; Zhao, Z.; Zhou, Y.; Liu, L. Nanoscale 2012, 4, 613. doi: 10.1039/c1nr11411e
20. [20]
  Qu, Q. T.; Fu, L. J.; Zhan, X. Y.; Samuelis, D.; Maier, J.; Li, L.; Tian, S.; Li, Z. H., Wu, Y. P. Energy Environ. Sci. 2011, 4, 3985. doi: 10.1039/c0ee00673d
21. [21]
  Yang, X. H.; Li, Z.; Sun, C. H.; Yang, H. G.; Li, C. Z. Chem. Mater. 2011, 23, 3486. doi: 10.1021/cm2008768
22. [22]
  Huang, Y. H. Acta Phys. -Chim. Sin. 2016, 32, 816. [黄云辉. 物理化学学报, 2016, 32, 816.] doi: 10.1021/cm2008768
23. [23]
  Zhao, R. Z.; Li, Q.; Wang, C. X.; Yin, L.W. Electrochim. Acta 2016, 197, 58. doi: 10.1016/j.electacta.2016.03.047
24. [24]
  Mo, Y. D.; Ru, Q.; Chen, J. F.; Song, X.; Guo, L. Y.; Hu, S.J.; Peng, S. M. J. Mater. Chem. A 2015, 3, 19765. doi: 10.1039/C5TA05931C
25. [25]
  Wang, Y. J.; Zhang, Y. Z.; Ou, J. K.; Zhao, Q.; Liao, M.; Xiao, D. RSC Adv. 2016, 6, 547. doi: 10.1039/c5ra21916g
26. [26]
  Song, X.; Ru, Q.; Zhang, B.; Hu, S.; An, B. J. Alloy. Compd. 2014, 585, 518. doi: 10.1016/j.jallcom.2014.03.190
27. [27]
  Xu, J. M.; He, L.; Wang, Y. J.; Zhang, C. J.; Zhang, Y. H. Electrochim. Acta 2016, 191, 417. doi: 10.1016/j.electacta.2016.01.023
28. [28]
  Huang, L.; Waller, G. H.; Ding, Y.; Chen, D.; Ding, D.; Xi, P.; Wang, Z. L.; Liu, M. Nano Energy 2015, 11, 64. doi: 10.1016/j.nanoen.2014.09.027
29. [29]
  Rai, A. K.; Thi, T. V.; Paul, B. J.; Kim, J. Electrochim. Acta 2014, 146, 577. doi: 10.1016/j.electacta.2014.09.079
30. [30]
  Zhong, X. B.; Wang, H. Y.; Yang, Z. Z.; Jin, B.; Jiang, Q. C. J. Power Sources 2015, 296, 298. doi: 10.1016/j.jpowsour.2015.07.047
31. [31]
  Zhang, Z. C.; Chen, Y. F.; He, S.; Zhang, J. C.; Xu, X. B.; Yang, Y.; Nosheen, F.; Saleem, F.; He, W.; Wang, X. Angew. Chem. Int. Edit. 2014, 53, 12517. doi: 10.1002/anie.201406484
32. [32]
  Luo, W.; Huang, L.; Guan, D. D.; He, R. H.; Li, F.; Mai, L. Q. Acta Phys. -Chim. Sin. 2016, 32, 1999. [罗雯, 黄磊, 关豆豆, 贺汝涵, 李枫, 麦立强. 物理化学学报, 2016, 32, 1999.] doi: 10.3866/PKU.WHXB20160532
33. [33]
  Liu, H.W.; Wang, J. Electrochim. Acta 2013, 92, 371. doi: 10.1016/j.electacta.2014.09.079
34. [34]
  Ru, Q.; Song, X.; Mo, Y. D.; Guo, L. Y.; Hu, S. J. J. Alloy. Compd. 2016, 654, 586. doi: 10.1016/j.jallcom.2015.09.105
35. [35]
  Varzi, A.; Bresser, D.; Zamory, J.; Müller, F.; Passerini, S. Adv. Energy Mater. 2014, 4, 1400054. doi: 10.1002/aenm.201400054
36. [36]
  Zou, F.; Hu, X.; Li, Z.; Qie, L.; Hu, C.; Zeng, R.; Jiang, Y.; Huang, Y. Adv. Mater. 2014, 26, 6622. doi: 10.1002/adma.201402322

扫一扫看文章

计量

PDF下载量: 2
文章访问数: 945
HTML全文浏览量: 165

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

三维介孔钴酸锌立方体的制备及其优异的储锂性能

English

Synthesis and Lithium Storage Performance of Three-Dimensional Mesostructured ZnCo₂O₄ Cubes

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

三维介孔钴酸锌立方体的制备及其优异的储锂性能

English

Synthesis and Lithium Storage Performance of Three-Dimensional Mesostructured ZnCo2O4 Cubes

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Synthesis and Lithium Storage Performance of Three-Dimensional Mesostructured ZnCo₂O₄ Cubes

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs