引用本文:
Xin Cui, Juan Li, Lei Liu, Qing Xiang Guo. 1, 3-Dicarbonyl compounds as phosphine-free ligands for Pd-catalyzed Heck and Suzuki reactions[J]. Chinese Chemical Letters,
2007, 18(6): 625-628.
doi:
10.1016/j.cclet.2007.04.014
Citation: Xin Cui, Juan Li, Lei Liu, Qing Xiang Guo. 1, 3-Dicarbonyl compounds as phosphine-free ligands for Pd-catalyzed Heck and Suzuki reactions[J]. Chinese Chemical Letters, 2007, 18(6): 625-628. doi: 10.1016/j.cclet.2007.04.014
Citation: Xin Cui, Juan Li, Lei Liu, Qing Xiang Guo. 1, 3-Dicarbonyl compounds as phosphine-free ligands for Pd-catalyzed Heck and Suzuki reactions[J]. Chinese Chemical Letters, 2007, 18(6): 625-628. doi: 10.1016/j.cclet.2007.04.014
1, 3-Dicarbonyl compounds as phosphine-free ligands for Pd-catalyzed Heck and Suzuki reactions
摘要:
Some 1, 3-dicarbonyl compounds (such as pentane-2, 4-dione and 3-oxo-N-phenylbutanamide) were found to constitute highly efficient, yet low-priced and phosphine-free ligands for the Pd-catalyzed Heck and Suzuki reactions of aryl bromides and iodides with very high turnover numbers (ca.103-104).
English
1, 3-Dicarbonyl compounds as phosphine-free ligands for Pd-catalyzed Heck and Suzuki reactions
Abstract:
Some 1, 3-dicarbonyl compounds (such as pentane-2, 4-dione and 3-oxo-N-phenylbutanamide) were found to constitute highly efficient, yet low-priced and phosphine-free ligands for the Pd-catalyzed Heck and Suzuki reactions of aryl bromides and iodides with very high turnover numbers (ca.103-104).
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Key words:
- Palladium catalyst
- / Suzuki reaction
- / Heck reaction
- / Phosphine-free ligand
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