引用本文:
Guo Bin RONG, Ru Jian MA, Chong Ying ZHOU, Zhu Liang JIN, Wan Nian WU, Qing WANG. The Preparation of Unsymmetrical Diaminodimethylsilanes and the Cleavage of Silicon-Nitrogen Bonds by Acid Chloride[J]. Chinese Chemical Letters,
1997, 8(11): 945-946.
Citation: Guo Bin RONG, Ru Jian MA, Chong Ying ZHOU, Zhu Liang JIN, Wan Nian WU, Qing WANG. The Preparation of Unsymmetrical Diaminodimethylsilanes and the Cleavage of Silicon-Nitrogen Bonds by Acid Chloride[J]. Chinese Chemical Letters, 1997, 8(11): 945-946.
Citation: Guo Bin RONG, Ru Jian MA, Chong Ying ZHOU, Zhu Liang JIN, Wan Nian WU, Qing WANG. The Preparation of Unsymmetrical Diaminodimethylsilanes and the Cleavage of Silicon-Nitrogen Bonds by Acid Chloride[J]. Chinese Chemical Letters, 1997, 8(11): 945-946.
The Preparation of Unsymmetrical Diaminodimethylsilanes and the Cleavage of Silicon-Nitrogen Bonds by Acid Chloride
摘要:
Seven unsymmetrical diaminodimethylsilanes were prepared.The reactions of these silylamine with benzoyl chloride indicated that in comparison with electronic,the steric effect played more important role on the reactivity of Si-N bond.As a new method,unsymmetrical diamide can be produced by the reaction of the title compounds with diacid chloride.
English
The Preparation of Unsymmetrical Diaminodimethylsilanes and the Cleavage of Silicon-Nitrogen Bonds by Acid Chloride
Abstract:
Seven unsymmetrical diaminodimethylsilanes were prepared.The reactions of these silylamine with benzoyl chloride indicated that in comparison with electronic,the steric effect played more important role on the reactivity of Si-N bond.As a new method,unsymmetrical diamide can be produced by the reaction of the title compounds with diacid chloride.
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